Ruthenium(III) Catalysis in Perborate Oxidation of 5-Oxoacids

Ruthenium(III) catalyzes perborate oxidation of substituted 5-oxoacids in acidic solution. The catalyzed oxidation is first order with respect to the oxidant and catalyst. The rate of ruthenium(III) catalyzed oxidation displays the Michaelis-Menten kinetics on the reductant and is independent of [H+...

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Veröffentlicht in:	Advances in Physical Chemistry 2014-01, Vol.2014 (2014), p.90-103
Hauptverfasser:	Shree Devi, S., Krishnamoorthy, P., Muthukumaran, B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Borates Catalysis Chemical properties Identification and classification Kinetics Oxidation Oxidation-reduction reaction Ruthenium Studies
Online-Zugang:	Volltext
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