On reaction pathways in the conversion of methanol to hydrocarbons on HZSM-5

[Display omitted] •MTO mechanism was explored under industrially relevant conditions on ZSM-5.•Olefin- and aromatic-based cycle contribution depends on local chemical potential.•Co-feeding small concentrations of higher alcohols significantly increased catalyst lifetime.•Hydride transfer involving m...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of catalysis 2014-08, Vol.317, p.185-197
Hauptverfasser:	Sun, Xianyong, Mueller, Sebastian, Liu, Yue, Shi, Hui, Haller, Gary L., Sanchez-Sanchez, Maricruz, van Veen, Andre C., Lercher, Johannes A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical reactions Chemistry Exact sciences and technology General and physical chemistry Hydrocarbon pool Hydrocarbons Ion-exchange Mechanism Methanol Methanol to olefins Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Zeolites: preparations and properties ZSM-5
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!