ChemInform Abstract: Using Rh(III)-Catalyzed C-H Activation as a Tool for the Selective Functionalization of Ketone-Containing Molecules

ChemInform Abstract: Using Rh(III)-Catalyzed C-H Activation as a Tool for the Selective Functionalization of Ketone-Containing Molecules

The dimethylcarbamoyl directing group in (IIIf) is cleaved using Schwartz reagent yielding the corresponding ketone in low yield.

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Veröffentlicht in:ChemInform 2014-08, Vol.45 (34), p.no-no
Hauptverfasser: Boultadakis-Arapinis, Melissa, Hopkinson, Matthew N., Glorius, Frank
Format: Artikel
Sprache:eng
Schlagworte:
alkenes (benzene compounds)
C-C bond formation
carbamic acid derivatives (benzene compounds)
catalysis
catalysis, phase‐transfer catalysis
e/z-selectivity (incl. e/z-isomerism)
esters of aliphatic acids
phase-transfer catalysis
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Zusammenfassung:The dimethylcarbamoyl directing group in (IIIf) is cleaved using Schwartz reagent yielding the corresponding ketone in low yield.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201434112