Pd-Catalyzed Threefold Arylation of Baylis-Hillman Bromides and Acetates with Triarylbismuth Reagents

Functionalized alkyl 2‐benzylacrylates and 2‐benzylacrylonitriles were synthesized by means of atom‐economic cross‐couplings of Baylis–Hillman bromides or acetates with BiAr3 under palladium‐catalyzed conditions. These reactions, involving threefold aryl couplings using BiAr3 reagents with bromides...

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Veröffentlicht in:	European journal of organic chemistry 2012-08, Vol.2012 (24), p.4580-4589
Hauptverfasser:	Rao, Maddali L. N., Giri, Somnath
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Alkenes Bismuth C-C coupling Chemistry Exact sciences and technology Organic chemistry Palladium Preparations and properties Synthetic methods
Online-Zugang:	Volltext
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