Isolation and Crystal Structure of the Proposed Low-Valent Active Species in the H2 Activation Catalytic Cycle
We provide confirmation of our proposed design principles for a H2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal–metal bond. A...
Gespeichert in:
| Veröffentlicht in: | European journal of inorganic chemistry 2013-08, Vol.2013 (22-23), p.3978-3986 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3986 |
|---|---|
| container_issue | 22-23 |
| container_start_page | 3978 |
| container_title | European journal of inorganic chemistry |
| container_volume | 2013 |
| creator | Inoki, Daisuke Matsumoto, Takahiro Nakai, Hidetaka Ogo, Seiji |
| description | We provide confirmation of our proposed design principles for a H2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal–metal bond.
A two‐electron‐reduced dinuclear IrII–IrII complex was synthesized by the reaction of a mononuclear IrIII aqua complex by extraction of electrons from H2 in water under ambient conditions. |
| doi_str_mv | 10.1002/ejic.201300049 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_journals_1529736292</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3317837301</sourcerecordid><originalsourceid>FETCH-LOGICAL-i2529-1aae36ea831f26f2e70796cb75b7b49ca40f908ef67a09acc7816f306efdf6e23</originalsourceid><addsrcrecordid>eNo9kEtPwzAQhCMEEqVw5WyJc8CP1I6PVdQXqgCpPI6W666FS0iK7VDy70kJ6ml3td_MSJMk1wTfEozpHWyduaWYMIxxJk-SAcFSppjn9LTbM5alRGb5eXIRwrZDGGZ8kFSLUJc6urpCutqgwrch6hKtom9MbDyg2qL4DujJ17s6wAYt6336qkuoIhqb6L4BrXZgHATkqj9yTvtHb1rozq6NzqCiNSVcJmdWlwGu_ucweZlOnot5unycLYrxMnV0RGVKtAbGQeeMWMotBYGF5GYtRmuxzqTRGbYS52C50FhqY0ROuGWYg91YDpQNk5ved-frrwZCVNu68VUXqUgXIBin8kDJntq7Elq18-5T-1YRrA6FqkOh6liomtwviuPVadNe60KEn6NW-w_FBRMj9fYwUyybjSibTRVjv35ve1k</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1529736292</pqid></control><display><type>article</type><title>Isolation and Crystal Structure of the Proposed Low-Valent Active Species in the H2 Activation Catalytic Cycle</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Inoki, Daisuke ; Matsumoto, Takahiro ; Nakai, Hidetaka ; Ogo, Seiji</creator><creatorcontrib>Inoki, Daisuke ; Matsumoto, Takahiro ; Nakai, Hidetaka ; Ogo, Seiji</creatorcontrib><description>We provide confirmation of our proposed design principles for a H2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal–metal bond.
A two‐electron‐reduced dinuclear IrII–IrII complex was synthesized by the reaction of a mononuclear IrIII aqua complex by extraction of electrons from H2 in water under ambient conditions.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.201300049</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Crystal structure ; Electron ; Hydrides ; Hydrogen ; Hydrogen activation ; Iridium ; Isotope exchange</subject><ispartof>European journal of inorganic chemistry, 2013-08, Vol.2013 (22-23), p.3978-3986</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejic.201300049$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejic.201300049$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Inoki, Daisuke</creatorcontrib><creatorcontrib>Matsumoto, Takahiro</creatorcontrib><creatorcontrib>Nakai, Hidetaka</creatorcontrib><creatorcontrib>Ogo, Seiji</creatorcontrib><title>Isolation and Crystal Structure of the Proposed Low-Valent Active Species in the H2 Activation Catalytic Cycle</title><title>European journal of inorganic chemistry</title><addtitle>Eur. J. Inorg. Chem</addtitle><description>We provide confirmation of our proposed design principles for a H2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal–metal bond.
A two‐electron‐reduced dinuclear IrII–IrII complex was synthesized by the reaction of a mononuclear IrIII aqua complex by extraction of electrons from H2 in water under ambient conditions.</description><subject>Crystal structure</subject><subject>Electron</subject><subject>Hydrides</subject><subject>Hydrogen</subject><subject>Hydrogen activation</subject><subject>Iridium</subject><subject>Isotope exchange</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNo9kEtPwzAQhCMEEqVw5WyJc8CP1I6PVdQXqgCpPI6W666FS0iK7VDy70kJ6ml3td_MSJMk1wTfEozpHWyduaWYMIxxJk-SAcFSppjn9LTbM5alRGb5eXIRwrZDGGZ8kFSLUJc6urpCutqgwrch6hKtom9MbDyg2qL4DujJ17s6wAYt6336qkuoIhqb6L4BrXZgHATkqj9yTvtHb1rozq6NzqCiNSVcJmdWlwGu_ucweZlOnot5unycLYrxMnV0RGVKtAbGQeeMWMotBYGF5GYtRmuxzqTRGbYS52C50FhqY0ROuGWYg91YDpQNk5ved-frrwZCVNu68VUXqUgXIBin8kDJntq7Elq18-5T-1YRrA6FqkOh6liomtwviuPVadNe60KEn6NW-w_FBRMj9fYwUyybjSibTRVjv35ve1k</recordid><startdate>201308</startdate><enddate>201308</enddate><creator>Inoki, Daisuke</creator><creator>Matsumoto, Takahiro</creator><creator>Nakai, Hidetaka</creator><creator>Ogo, Seiji</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201308</creationdate><title>Isolation and Crystal Structure of the Proposed Low-Valent Active Species in the H2 Activation Catalytic Cycle</title><author>Inoki, Daisuke ; Matsumoto, Takahiro ; Nakai, Hidetaka ; Ogo, Seiji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i2529-1aae36ea831f26f2e70796cb75b7b49ca40f908ef67a09acc7816f306efdf6e23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Crystal structure</topic><topic>Electron</topic><topic>Hydrides</topic><topic>Hydrogen</topic><topic>Hydrogen activation</topic><topic>Iridium</topic><topic>Isotope exchange</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Inoki, Daisuke</creatorcontrib><creatorcontrib>Matsumoto, Takahiro</creatorcontrib><creatorcontrib>Nakai, Hidetaka</creatorcontrib><creatorcontrib>Ogo, Seiji</creatorcontrib><collection>Istex</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Inoki, Daisuke</au><au>Matsumoto, Takahiro</au><au>Nakai, Hidetaka</au><au>Ogo, Seiji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isolation and Crystal Structure of the Proposed Low-Valent Active Species in the H2 Activation Catalytic Cycle</atitle><jtitle>European journal of inorganic chemistry</jtitle><addtitle>Eur. J. Inorg. Chem</addtitle><date>2013-08</date><risdate>2013</risdate><volume>2013</volume><issue>22-23</issue><spage>3978</spage><epage>3986</epage><pages>3978-3986</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>We provide confirmation of our proposed design principles for a H2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal–metal bond.
A two‐electron‐reduced dinuclear IrII–IrII complex was synthesized by the reaction of a mononuclear IrIII aqua complex by extraction of electrons from H2 in water under ambient conditions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.201300049</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1434-1948 |
| ispartof | European journal of inorganic chemistry, 2013-08, Vol.2013 (22-23), p.3978-3986 |
| issn | 1434-1948 1099-0682 |
| language | eng |
| recordid | cdi_proquest_journals_1529736292 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Crystal structure Electron Hydrides Hydrogen Hydrogen activation Iridium Isotope exchange |
| title | Isolation and Crystal Structure of the Proposed Low-Valent Active Species in the H2 Activation Catalytic Cycle |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-20T16%3A39%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Isolation%20and%20Crystal%20Structure%20of%20the%20Proposed%20Low-Valent%20Active%20Species%20in%20the%20H2%20Activation%20Catalytic%20Cycle&rft.jtitle=European%20journal%20of%20inorganic%20chemistry&rft.au=Inoki,%20Daisuke&rft.date=2013-08&rft.volume=2013&rft.issue=22-23&rft.spage=3978&rft.epage=3986&rft.pages=3978-3986&rft.issn=1434-1948&rft.eissn=1099-0682&rft_id=info:doi/10.1002/ejic.201300049&rft_dat=%3Cproquest_wiley%3E3317837301%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1529736292&rft_id=info:pmid/&rfr_iscdi=true |