Chemical Analysis of High-Level Radioactive Waste Glass by ICP-AES

The chemical composition of the high-level radioactive waste glass which was produced in the Windscale Vitrification Plant at Sellafield was determined by ICP-AES. The chemical analysis was performed in shielded cells and glove boxes at the Japan Atomic Energy Research Institute. The sample was diss...

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Veröffentlicht in:Analytical Sciences 1998, Vol.14(2), pp.389-394
Hauptverfasser: BANBA, Tsunetaka, HAGIYA, Hiromichi, TAMURA, Yukito, SENOO, Muneaki, YONEZAWA, Chushiro, CARTER, Paul B.
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container_end_page 394
container_issue 2
container_start_page 389
container_title Analytical Sciences
container_volume 14
creator BANBA, Tsunetaka
HAGIYA, Hiromichi
TAMURA, Yukito
SENOO, Muneaki
YONEZAWA, Chushiro
CARTER, Paul B.
description The chemical composition of the high-level radioactive waste glass which was produced in the Windscale Vitrification Plant at Sellafield was determined by ICP-AES. The chemical analysis was performed in shielded cells and glove boxes at the Japan Atomic Energy Research Institute. The sample was dissolved by alkaline fusion with sodium peroxide and acidic decomposition with hydrofluoric and perchloric acids for determining Si and B, and Li, Na, Mg, Al, P, Cr, Fe, Ni, Sr, Zr, Mo, La, Ce, Nd and U, respectively. High accuracy of the analytical results was confirmed by analyzing the refer-ence material of glass (NIST SRM1412) and a simulated inactive waste glass. The analytical results of the high-level radioactive waste glass were in good or fair agreement with the values estimated by British Nuclear Fuels plc, which were calculated from the analytical data of the high-level radioactive liquid waste and glass frit used in the production of the radioactive waste glass.
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subjects Analytical chemistry
Applied sciences
Chemistry
Exact sciences and technology
Pollution
Radioactive wastes
Spectrometric and optical methods
Wastes
title Chemical Analysis of High-Level Radioactive Waste Glass by ICP-AES
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