Enantioselective Palladium-Catalyzed Insertion of [alpha]-Aryl-[alpha]-diazoacetates into the OH Bonds of Phenols

A palladium-catalyzed asymmetric OH insertion reaction was developed. Palladium complexes with chiral spiro bisoxazoline ligands promoted the insertion of [alpha]-aryl-[alpha]-diazoacetates into the OH bond of phenols with high yield and excellent enantioselectivity under mild reaction conditions. T...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-03, Vol.53 (11), p.2978
Hauptverfasser:	Xie, Xiu-Lan, Zhu, Shou-Fei, Guo, Jun-Xia, Cai, Yan, Zhou, Qi-Lin
Format:	Artikel
Sprache:	eng
Schlagworte:	Phenols
Online-Zugang:	Volltext
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