Enantioselective Palladium-Catalyzed Insertion of [alpha]-Aryl-[alpha]-diazoacetates into the OH Bonds of Phenols

Enantioselective Palladium-Catalyzed Insertion of [alpha]-Aryl-[alpha]-diazoacetates into the OH Bonds of Phenols

A palladium-catalyzed asymmetric OH insertion reaction was developed. Palladium complexes with chiral spiro bisoxazoline ligands promoted the insertion of [alpha]-aryl-[alpha]-diazoacetates into the OH bond of phenols with high yield and excellent enantioselectivity under mild reaction conditions. T...

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Veröffentlicht in:Angewandte Chemie International Edition 2014-03, Vol.53 (11), p.2978
Hauptverfasser: Xie, Xiu-Lan, Zhu, Shou-Fei, Guo, Jun-Xia, Cai, Yan, Zhou, Qi-Lin
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Phenols
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container_issue 11
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container_title Angewandte Chemie International Edition
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creator Xie, Xiu-Lan
Zhu, Shou-Fei
Guo, Jun-Xia
Cai, Yan
Zhou, Qi-Lin
description A palladium-catalyzed asymmetric OH insertion reaction was developed. Palladium complexes with chiral spiro bisoxazoline ligands promoted the insertion of [alpha]-aryl-[alpha]-diazoacetates into the OH bond of phenols with high yield and excellent enantioselectivity under mild reaction conditions. This palladium-catalyzed asymmetric OH insertion reaction provided an efficient and highly enantioselective method for the preparation of synthetically useful optically active [alpha]-aryl-[alpha]-aryloxyacetates. [PUBLICATION ABSTRACT]
doi_str_mv 10.1002/anie.201309820
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title Enantioselective Palladium-Catalyzed Insertion of [alpha]-Aryl-[alpha]-diazoacetates into the OH Bonds of Phenols
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