Cyclic wetting–drying ageing test and patina formation on tuffeau limestone
This paper presents the results of an ageing test based on cycles of wetting–drying of a French building limestone named tuffeau. During 3 years, 50 complete wetting–drying cycles with pure distilled water were carried out on the side of a cylindrical sample. The characterization of the stone shows...
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Veröffentlicht in: | Environmental earth sciences 2014-03, Vol.71 (5), p.2361-2372 |
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description | This paper presents the results of an ageing test based on cycles of wetting–drying of a French building limestone named tuffeau. During 3 years, 50 complete wetting–drying cycles with pure distilled water were carried out on the side of a cylindrical sample. The characterization of the stone shows that the ageing test applied induces changes in the surface appearance, with the formation of a patina with decrease in porosity and mineralogical changes due to dissolution, transport, and recrystallization of the dissolved mineralogical component of the rock as calcite. The decrease in the imbibition kinetics confirms the alteration of the tested stone sample. After 50 wetting–drying cycles, imbibition coefficients are almost halved. This alteration is not homogeneous as the patina covers only some sections of the exposed surface of the stone. On the well-formed parts of the patina with a brownish and varnished aspect, which represent about 20 % of the total surface, measurements show a decrease in porosity and roughness of about 25 %. The physico-chemical characterization shows that the patina formed in the laboratory is fully comparable to natural patina observed on monuments built of tuffeau. |
doi_str_mv | 10.1007/s12665-013-2637-z |
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During 3 years, 50 complete wetting–drying cycles with pure distilled water were carried out on the side of a cylindrical sample. The characterization of the stone shows that the ageing test applied induces changes in the surface appearance, with the formation of a patina with decrease in porosity and mineralogical changes due to dissolution, transport, and recrystallization of the dissolved mineralogical component of the rock as calcite. The decrease in the imbibition kinetics confirms the alteration of the tested stone sample. After 50 wetting–drying cycles, imbibition coefficients are almost halved. This alteration is not homogeneous as the patina covers only some sections of the exposed surface of the stone. On the well-formed parts of the patina with a brownish and varnished aspect, which represent about 20 % of the total surface, measurements show a decrease in porosity and roughness of about 25 %. The physico-chemical characterization shows that the patina formed in the laboratory is fully comparable to natural patina observed on monuments built of tuffeau.</description><identifier>ISSN: 1866-6280</identifier><identifier>EISSN: 1866-6299</identifier><identifier>DOI: 10.1007/s12665-013-2637-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Biogeosciences ; Calcite ; Distilled water ; Drying ; Earth and Environmental Science ; Earth Sciences ; Earth, ocean, space ; Engineering and environment geology. 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During 3 years, 50 complete wetting–drying cycles with pure distilled water were carried out on the side of a cylindrical sample. The characterization of the stone shows that the ageing test applied induces changes in the surface appearance, with the formation of a patina with decrease in porosity and mineralogical changes due to dissolution, transport, and recrystallization of the dissolved mineralogical component of the rock as calcite. The decrease in the imbibition kinetics confirms the alteration of the tested stone sample. After 50 wetting–drying cycles, imbibition coefficients are almost halved. This alteration is not homogeneous as the patina covers only some sections of the exposed surface of the stone. On the well-formed parts of the patina with a brownish and varnished aspect, which represent about 20 % of the total surface, measurements show a decrease in porosity and roughness of about 25 %. The physico-chemical characterization shows that the patina formed in the laboratory is fully comparable to natural patina observed on monuments built of tuffeau.</description><subject>Biogeosciences</subject><subject>Calcite</subject><subject>Distilled water</subject><subject>Drying</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Earth, ocean, space</subject><subject>Engineering and environment geology. Geothermics</subject><subject>Engineering geology</subject><subject>Environmental Science and Engineering</subject><subject>Exact sciences and technology</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Hydrology/Water Resources</subject><subject>Limestone</subject><subject>Original Article</subject><subject>Porosity</subject><subject>Terrestrial Pollution</subject><issn>1866-6280</issn><issn>1866-6299</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1UMtKA0EQHETBEPMB3hbE4-o8dmdnjhJ8QcSLnofOPMKGzW6c2SDJyX_wD_0SO2wIXhwGuqCqq4si5JLRG0ZpdZsYl7LMKRM5l6LKdydkxJSUueRanx6xoudkktKS4hNMaCpH5GW6tU1ts0_f93W7-Pn6dnGLIIOF34_epz6D1mVrQB6y0MUVoq7N8PebEDxssqZeoaxr_QU5C9AkPznMMXl_uH-bPuWz18fn6d0sByF1n3ulqrLAuFxUpdI0BOWsk6IIc07nhedQgrbgnBXOMidcxUolwZVBIytBjMnV4LuO3ccGb5tlt4ktnjSs0FJV6MtRxQaVjV1K0QezjvUK4tYwavbFmaE4g0nMvjizw53rgzMkC02I0No6HRe54hVVVKGOD7qEVLvw8U-Cf81_Ac9Cf3U</recordid><startdate>20140301</startdate><enddate>20140301</enddate><creator>Beck, K.</creator><creator>Al-Mukhtar, M.</creator><general>Springer Berlin Heidelberg</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7TG</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H96</scope><scope>HCIFZ</scope><scope>KL.</scope><scope>L.G</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope></search><sort><creationdate>20140301</creationdate><title>Cyclic wetting–drying ageing test and patina formation on tuffeau limestone</title><author>Beck, K. ; Al-Mukhtar, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a369t-e887540132375890ff8dcd634fb20b4e2a5a9caddc3dc1d3d71586ad5f9b4e6a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Biogeosciences</topic><topic>Calcite</topic><topic>Distilled water</topic><topic>Drying</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Earth, ocean, space</topic><topic>Engineering and environment geology. Geothermics</topic><topic>Engineering geology</topic><topic>Environmental Science and Engineering</topic><topic>Exact sciences and technology</topic><topic>Geochemistry</topic><topic>Geology</topic><topic>Hydrology/Water Resources</topic><topic>Limestone</topic><topic>Original Article</topic><topic>Porosity</topic><topic>Terrestrial Pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Beck, K.</creatorcontrib><creatorcontrib>Al-Mukhtar, M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Environment Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Water Resources Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>SciTech Premium Collection</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Environment Abstracts</collection><jtitle>Environmental earth sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Beck, K.</au><au>Al-Mukhtar, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cyclic wetting–drying ageing test and patina formation on tuffeau limestone</atitle><jtitle>Environmental earth sciences</jtitle><stitle>Environ Earth Sci</stitle><date>2014-03-01</date><risdate>2014</risdate><volume>71</volume><issue>5</issue><spage>2361</spage><epage>2372</epage><pages>2361-2372</pages><issn>1866-6280</issn><eissn>1866-6299</eissn><abstract>This paper presents the results of an ageing test based on cycles of wetting–drying of a French building limestone named tuffeau. During 3 years, 50 complete wetting–drying cycles with pure distilled water were carried out on the side of a cylindrical sample. The characterization of the stone shows that the ageing test applied induces changes in the surface appearance, with the formation of a patina with decrease in porosity and mineralogical changes due to dissolution, transport, and recrystallization of the dissolved mineralogical component of the rock as calcite. The decrease in the imbibition kinetics confirms the alteration of the tested stone sample. After 50 wetting–drying cycles, imbibition coefficients are almost halved. This alteration is not homogeneous as the patina covers only some sections of the exposed surface of the stone. On the well-formed parts of the patina with a brownish and varnished aspect, which represent about 20 % of the total surface, measurements show a decrease in porosity and roughness of about 25 %. The physico-chemical characterization shows that the patina formed in the laboratory is fully comparable to natural patina observed on monuments built of tuffeau.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s12665-013-2637-z</doi><tpages>12</tpages></addata></record> |
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subjects | Biogeosciences Calcite Distilled water Drying Earth and Environmental Science Earth Sciences Earth, ocean, space Engineering and environment geology. Geothermics Engineering geology Environmental Science and Engineering Exact sciences and technology Geochemistry Geology Hydrology/Water Resources Limestone Original Article Porosity Terrestrial Pollution |
title | Cyclic wetting–drying ageing test and patina formation on tuffeau limestone |
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