Effect of phenol functionalized carbon nanotube on mechanical, dynamic mechanical, and thermal properties of isotactic polypropylene nanocomposites
In this work, multiwall carbon nanotubes (MWCNT) were functionalized with phenol and characterized by using Fourier transform infrared spectroscopy (FTIR). Isotactic polypropylene (iPP)/MWCNT composites of both the unfunctionalized and functionalized MWCNT were prepared by melt blending in a miniext...
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| Veröffentlicht in: | Polymer engineering and science 2012-03, Vol.52 (3), p.525-531 |
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| creator | P., Selvin Thomas Girei, Salihu Adamu Al-Juhani, Abdulhadi A. Mezghani, Khaled De, S.K. Atieh, Muataz Ali |
| description | In this work, multiwall carbon nanotubes (MWCNT) were functionalized with phenol and characterized by using Fourier transform infrared spectroscopy (FTIR). Isotactic polypropylene (iPP)/MWCNT composites of both the unfunctionalized and functionalized MWCNT were prepared by melt blending in a miniextruder at different loadings of nanotubes (i.e., 0.1, 0.25, 1.0, and 5.0 wt%). The tensile properties of the composites were found to increase with increase in nanotube loading with a maximum in Young's modulus being achieved at 1.0 wt% loading of phenol functionalized MWCNT. The differential scanning calorimetry (DSC) studies reveal the nucleating effect of MWCNT on the crystallization of iPP. Percentage crystallinity was found to increase on phenol functionalization of MWCNT. Results of X‐ray diffraction studies of the composites are in conformity with that of DSC studies. Dynamic mechanical studies reveal that the functionalized MWCNT causes many fold increase in the storage modulus, and the effect is pronounced in the case of functionalized MWCNT. POLYM. ENG. SCI. 2012. © 2011 Society of Plastics Engineers |
| doi_str_mv | 10.1002/pen.22113 |
| format | Article |
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Isotactic polypropylene (iPP)/MWCNT composites of both the unfunctionalized and functionalized MWCNT were prepared by melt blending in a miniextruder at different loadings of nanotubes (i.e., 0.1, 0.25, 1.0, and 5.0 wt%). The tensile properties of the composites were found to increase with increase in nanotube loading with a maximum in Young's modulus being achieved at 1.0 wt% loading of phenol functionalized MWCNT. The differential scanning calorimetry (DSC) studies reveal the nucleating effect of MWCNT on the crystallization of iPP. Percentage crystallinity was found to increase on phenol functionalization of MWCNT. Results of X‐ray diffraction studies of the composites are in conformity with that of DSC studies. Dynamic mechanical studies reveal that the functionalized MWCNT causes many fold increase in the storage modulus, and the effect is pronounced in the case of functionalized MWCNT. POLYM. ENG. SCI. 2012. © 2011 Society of Plastics Engineers</description><identifier>ISSN: 0032-3888</identifier><identifier>EISSN: 1548-2634</identifier><identifier>DOI: 10.1002/pen.22113</identifier><identifier>CODEN: PYESAZ</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Carbon ; Chemical properties ; Composites ; Composition ; Crystallization ; Differential scanning calorimetry ; Diffraction ; Exact sciences and technology ; Forms of application and semi-finished materials ; Fourier transforms ; Mechanical properties ; Nanotubes ; Phenols ; Polymer industry, paints, wood ; Polymeric composites ; Polypropylene ; Spectrum analysis ; Technology of polymers ; Thermal properties</subject><ispartof>Polymer engineering and science, 2012-03, Vol.52 (3), p.525-531</ispartof><rights>Copyright © 2011 Society of Plastics Engineers</rights><rights>2014 INIST-CNRS</rights><rights>COPYRIGHT 2012 Society of Plastics Engineers, Inc.</rights><rights>Copyright Blackwell Publishing Ltd. 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Isotactic polypropylene (iPP)/MWCNT composites of both the unfunctionalized and functionalized MWCNT were prepared by melt blending in a miniextruder at different loadings of nanotubes (i.e., 0.1, 0.25, 1.0, and 5.0 wt%). The tensile properties of the composites were found to increase with increase in nanotube loading with a maximum in Young's modulus being achieved at 1.0 wt% loading of phenol functionalized MWCNT. The differential scanning calorimetry (DSC) studies reveal the nucleating effect of MWCNT on the crystallization of iPP. Percentage crystallinity was found to increase on phenol functionalization of MWCNT. Results of X‐ray diffraction studies of the composites are in conformity with that of DSC studies. Dynamic mechanical studies reveal that the functionalized MWCNT causes many fold increase in the storage modulus, and the effect is pronounced in the case of functionalized MWCNT. POLYM. ENG. SCI. 2012. © 2011 Society of Plastics Engineers</description><subject>Applied sciences</subject><subject>Carbon</subject><subject>Chemical properties</subject><subject>Composites</subject><subject>Composition</subject><subject>Crystallization</subject><subject>Differential scanning calorimetry</subject><subject>Diffraction</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Fourier transforms</subject><subject>Mechanical properties</subject><subject>Nanotubes</subject><subject>Phenols</subject><subject>Polymer industry, paints, wood</subject><subject>Polymeric composites</subject><subject>Polypropylene</subject><subject>Spectrum analysis</subject><subject>Technology of polymers</subject><subject>Thermal properties</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><recordid>eNp1kttuEzEQhlcIJELhgjdYCXGB1E19zO5eliqklaJyKkLqjTXr2InLrr3YXkH6GrwwzoFCpCBLtjX-_t-e8WTZS4zGGCFy1is7JgRj-igbYc6qgkwoe5yNEKKkoFVVPc2ehXCHEkt5Pcp-TbVWMuZO5_1KWdfmerAyGmehNfdqkUvwjbO5Bevi0Kg87TslV2CNhPY0X6wtdEYexMAu8rhSvoM2773rlY9Ghc0VJrgIyV3mvWvXm7N1q6zaukvX9S6YqMLz7ImGNqgX-_Uk-_JuenNxWczfz64uzueF5AzTAjfACS0R4hKzirGaAINSIsoIr4HVHDFUccxJ2UhEGqpKhHW50A1NICOInmSvdr7pId8HFaK4c4NPiQeBk7xO2pr8pZbQKmGsdtGD7EyQ4pxUhBPCcJWo4gi1TMl5aJ1V2qTwAT8-wqexUKmcRwVvDgSJiepnXMIQgrj6_OmQPf2HbYZgrAppCma5imEnOWYtvQvBKy16bzrwa4GR2HSVSF0ltl2V2Nf7mkFIn609WGnCg4Dw1HPlljvbcT9SHuv_G4oP0-s_zvsKmpASe1CA_yYmJS25-Ho9E7e3N7MJezsXH-lvWiHoqQ</recordid><startdate>201203</startdate><enddate>201203</enddate><creator>P., Selvin Thomas</creator><creator>Girei, Salihu Adamu</creator><creator>Al-Juhani, Abdulhadi A.</creator><creator>Mezghani, Khaled</creator><creator>De, S.K.</creator><creator>Atieh, Muataz Ali</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>ISR</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201203</creationdate><title>Effect of phenol functionalized carbon nanotube on mechanical, dynamic mechanical, and thermal properties of isotactic polypropylene nanocomposites</title><author>P., Selvin Thomas ; Girei, Salihu Adamu ; Al-Juhani, Abdulhadi A. ; Mezghani, Khaled ; De, S.K. ; Atieh, Muataz Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5413-1ba5237005c1484492a4a7c034259a495040851527bc02b3e701f7dfb32a44203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Carbon</topic><topic>Chemical properties</topic><topic>Composites</topic><topic>Composition</topic><topic>Crystallization</topic><topic>Differential scanning calorimetry</topic><topic>Diffraction</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Fourier transforms</topic><topic>Mechanical properties</topic><topic>Nanotubes</topic><topic>Phenols</topic><topic>Polymer industry, paints, wood</topic><topic>Polymeric composites</topic><topic>Polypropylene</topic><topic>Spectrum analysis</topic><topic>Technology of polymers</topic><topic>Thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>P., Selvin Thomas</creatorcontrib><creatorcontrib>Girei, Salihu Adamu</creatorcontrib><creatorcontrib>Al-Juhani, Abdulhadi A.</creatorcontrib><creatorcontrib>Mezghani, Khaled</creatorcontrib><creatorcontrib>De, S.K.</creatorcontrib><creatorcontrib>Atieh, Muataz Ali</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale Business: Insights</collection><collection>Business Insights: Essentials</collection><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer engineering and science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>P., Selvin Thomas</au><au>Girei, Salihu Adamu</au><au>Al-Juhani, Abdulhadi A.</au><au>Mezghani, Khaled</au><au>De, S.K.</au><au>Atieh, Muataz Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of phenol functionalized carbon nanotube on mechanical, dynamic mechanical, and thermal properties of isotactic polypropylene nanocomposites</atitle><jtitle>Polymer engineering and science</jtitle><addtitle>Polym Eng Sci</addtitle><date>2012-03</date><risdate>2012</risdate><volume>52</volume><issue>3</issue><spage>525</spage><epage>531</epage><pages>525-531</pages><issn>0032-3888</issn><eissn>1548-2634</eissn><coden>PYESAZ</coden><abstract>In this work, multiwall carbon nanotubes (MWCNT) were functionalized with phenol and characterized by using Fourier transform infrared spectroscopy (FTIR). Isotactic polypropylene (iPP)/MWCNT composites of both the unfunctionalized and functionalized MWCNT were prepared by melt blending in a miniextruder at different loadings of nanotubes (i.e., 0.1, 0.25, 1.0, and 5.0 wt%). The tensile properties of the composites were found to increase with increase in nanotube loading with a maximum in Young's modulus being achieved at 1.0 wt% loading of phenol functionalized MWCNT. The differential scanning calorimetry (DSC) studies reveal the nucleating effect of MWCNT on the crystallization of iPP. Percentage crystallinity was found to increase on phenol functionalization of MWCNT. Results of X‐ray diffraction studies of the composites are in conformity with that of DSC studies. Dynamic mechanical studies reveal that the functionalized MWCNT causes many fold increase in the storage modulus, and the effect is pronounced in the case of functionalized MWCNT. POLYM. ENG. 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| subjects | Applied sciences Carbon Chemical properties Composites Composition Crystallization Differential scanning calorimetry Diffraction Exact sciences and technology Forms of application and semi-finished materials Fourier transforms Mechanical properties Nanotubes Phenols Polymer industry, paints, wood Polymeric composites Polypropylene Spectrum analysis Technology of polymers Thermal properties |
| title | Effect of phenol functionalized carbon nanotube on mechanical, dynamic mechanical, and thermal properties of isotactic polypropylene nanocomposites |
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