Structure-property relationship studies in amine functionalized multiwall carbon nanotubes filled polypropylene composite fiber
Amine functionalized multiwalled carbon nanotubes (a‐MWNT) based polypropylene (PP) composite fibers were prepared in the presence of polypropylene‐g‐maleic anhydride (PP‐g‐MA) by melt‐mixing followed by melt‐spinning with subsequent post‐drawing of the as‐spun fibers of varying draw ratio (DR). In...
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| Veröffentlicht in: | Polymer engineering and science 2012-06, Vol.52 (6), p.1183-1194 |
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| creator | Tambe, Pankaj B. Bhattacharyya, Arup R. Kamath, Srikanth S. Kulkarni, Ajit R. Sreekumar, T.V. Srivastav, Anurag Rao, K.U. Bhasker Liu, Yaodong Kumar, Satish |
| description | Amine functionalized multiwalled carbon nanotubes (a‐MWNT) based polypropylene (PP) composite fibers were prepared in the presence of polypropylene‐g‐maleic anhydride (PP‐g‐MA) by melt‐mixing followed by melt‐spinning with subsequent post‐drawing of the as‐spun fibers of varying draw ratio (DR). In order to enhance the interfacial interaction, a‐MWNT were utilized in combination with PP‐g‐MA during melt‐mixing. Fourier transform infrared spectroscopic analysis revealed the formation of imide bonds between MA functionality of PP‐g‐MA and amine functional group of a‐MWNT. Higher tensile properties of PP/a‐MWNT/PP‐g‐MA composite fibers were registered with varying DR of the as‐spun fiber. Orientation factors of a‐MWNT and PP chains along the fiber axis were correlated with the higher tensile modulus and tensile strength of PP/a‐MWNT/PP‐g‐MA composite fiber of varying DR. Crystallization studies indicated the role of hetero‐nucleating action of a‐MWNT in PP/a‐MWNT/PP‐g‐MA composite fiber. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers |
| doi_str_mv | 10.1002/pen.22186 |
| format | Article |
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Bhasker ; Liu, Yaodong ; Kumar, Satish</creator><creatorcontrib>Tambe, Pankaj B. ; Bhattacharyya, Arup R. ; Kamath, Srikanth S. ; Kulkarni, Ajit R. ; Sreekumar, T.V. ; Srivastav, Anurag ; Rao, K.U. Bhasker ; Liu, Yaodong ; Kumar, Satish</creatorcontrib><description>Amine functionalized multiwalled carbon nanotubes (a‐MWNT) based polypropylene (PP) composite fibers were prepared in the presence of polypropylene‐g‐maleic anhydride (PP‐g‐MA) by melt‐mixing followed by melt‐spinning with subsequent post‐drawing of the as‐spun fibers of varying draw ratio (DR). In order to enhance the interfacial interaction, a‐MWNT were utilized in combination with PP‐g‐MA during melt‐mixing. Fourier transform infrared spectroscopic analysis revealed the formation of imide bonds between MA functionality of PP‐g‐MA and amine functional group of a‐MWNT. Higher tensile properties of PP/a‐MWNT/PP‐g‐MA composite fibers were registered with varying DR of the as‐spun fiber. Orientation factors of a‐MWNT and PP chains along the fiber axis were correlated with the higher tensile modulus and tensile strength of PP/a‐MWNT/PP‐g‐MA composite fiber of varying DR. Crystallization studies indicated the role of hetero‐nucleating action of a‐MWNT in PP/a‐MWNT/PP‐g‐MA composite fiber. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers</description><identifier>ISSN: 0032-3888</identifier><identifier>EISSN: 1548-2634</identifier><identifier>DOI: 10.1002/pen.22186</identifier><identifier>CODEN: PYESAZ</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Amines ; Applied sciences ; Chemical processes ; Chemical properties ; Composite materials ; Composition ; Crystallization ; Exact sciences and technology ; Identification and classification ; Nanotubes ; Physicochemistry of polymers ; Polymer industry, paints, wood ; Polypropylene ; Polypropylene fibers ; Production processes ; Spectrum analysis ; Technology of polymers ; Tensile strength</subject><ispartof>Polymer engineering and science, 2012-06, Vol.52 (6), p.1183-1194</ispartof><rights>Copyright © 2011 Society of Plastics Engineers</rights><rights>2014 INIST-CNRS</rights><rights>COPYRIGHT 2012 Society of Plastics Engineers, Inc.</rights><rights>Copyright Blackwell Publishing Ltd. Jun 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5416-e09cbfdb305bc086afd2f89c24bb55e2dafc185b10d0b12571ff3f29468bba2c3</citedby><cites>FETCH-LOGICAL-c5416-e09cbfdb305bc086afd2f89c24bb55e2dafc185b10d0b12571ff3f29468bba2c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpen.22186$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpen.22186$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25900181$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Tambe, Pankaj B.</creatorcontrib><creatorcontrib>Bhattacharyya, Arup R.</creatorcontrib><creatorcontrib>Kamath, Srikanth S.</creatorcontrib><creatorcontrib>Kulkarni, Ajit R.</creatorcontrib><creatorcontrib>Sreekumar, T.V.</creatorcontrib><creatorcontrib>Srivastav, Anurag</creatorcontrib><creatorcontrib>Rao, K.U. Bhasker</creatorcontrib><creatorcontrib>Liu, Yaodong</creatorcontrib><creatorcontrib>Kumar, Satish</creatorcontrib><title>Structure-property relationship studies in amine functionalized multiwall carbon nanotubes filled polypropylene composite fiber</title><title>Polymer engineering and science</title><addtitle>Polym Eng Sci</addtitle><description>Amine functionalized multiwalled carbon nanotubes (a‐MWNT) based polypropylene (PP) composite fibers were prepared in the presence of polypropylene‐g‐maleic anhydride (PP‐g‐MA) by melt‐mixing followed by melt‐spinning with subsequent post‐drawing of the as‐spun fibers of varying draw ratio (DR). In order to enhance the interfacial interaction, a‐MWNT were utilized in combination with PP‐g‐MA during melt‐mixing. Fourier transform infrared spectroscopic analysis revealed the formation of imide bonds between MA functionality of PP‐g‐MA and amine functional group of a‐MWNT. Higher tensile properties of PP/a‐MWNT/PP‐g‐MA composite fibers were registered with varying DR of the as‐spun fiber. Orientation factors of a‐MWNT and PP chains along the fiber axis were correlated with the higher tensile modulus and tensile strength of PP/a‐MWNT/PP‐g‐MA composite fiber of varying DR. Crystallization studies indicated the role of hetero‐nucleating action of a‐MWNT in PP/a‐MWNT/PP‐g‐MA composite fiber. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers</description><subject>Amines</subject><subject>Applied sciences</subject><subject>Chemical processes</subject><subject>Chemical properties</subject><subject>Composite materials</subject><subject>Composition</subject><subject>Crystallization</subject><subject>Exact sciences and technology</subject><subject>Identification and classification</subject><subject>Nanotubes</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Polypropylene</subject><subject>Polypropylene fibers</subject><subject>Production processes</subject><subject>Spectrum analysis</subject><subject>Technology of polymers</subject><subject>Tensile strength</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><recordid>eNp1ks9vFCEcxSdGE9fqwf9gEuPBxNnyY5hljrWptclaja3RGwEGtlQGpsCkTi_912XdtbrJGhI48HkvvC-vKF5CMIcAoMNBuTlCkDaPihkkNa1Qg-vHxQwAjCpMKX1aPIvxGmQWk3ZW3F-kMMo0BlUNwQ8qpKkMyvJkvItXZihjGjujYmlcyXvjVKlHJ9e33Jo71ZX9aJO55daWkgfhXem482kUWaKNtZkYvJ3W3pNVWS59P_hoUjYyQoXnxRPNbVQvtudB8fX9yeXxh2r56fTs-GhZSVLDplKglUJ3AgMiJKAN1x3StJWoFoIQhTquJaREQNABARFZQK2xRm3dUCE4kvigeLXxzS-5GVVM7NqPIYeIDNYtaQlEoPlLrbhVzDjtU-CyN1GyI9RC2tYUt5mq9lCrnC5w653KudUuP9_D59Wp3si9gjc7gswk9TOt-BgjO7v4ssu-_YcVY8x_FPMWzeoqxY1kn7UMPsagNBuC6XmYGARs3SCWG8R-Nyizr7cz41FyqwN30sQHASItAJDCzB1uuNucY_q_Ift8cv7HeTtBE3OwBwUPP1izwAvCvp2fMvx9CRfvLj8yjH8BMXnlTA</recordid><startdate>201206</startdate><enddate>201206</enddate><creator>Tambe, Pankaj B.</creator><creator>Bhattacharyya, Arup R.</creator><creator>Kamath, Srikanth S.</creator><creator>Kulkarni, Ajit R.</creator><creator>Sreekumar, T.V.</creator><creator>Srivastav, Anurag</creator><creator>Rao, K.U. Bhasker</creator><creator>Liu, Yaodong</creator><creator>Kumar, Satish</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>ISR</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201206</creationdate><title>Structure-property relationship studies in amine functionalized multiwall carbon nanotubes filled polypropylene composite fiber</title><author>Tambe, Pankaj B. ; Bhattacharyya, Arup R. ; Kamath, Srikanth S. ; Kulkarni, Ajit R. ; Sreekumar, T.V. ; Srivastav, Anurag ; Rao, K.U. 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Fourier transform infrared spectroscopic analysis revealed the formation of imide bonds between MA functionality of PP‐g‐MA and amine functional group of a‐MWNT. Higher tensile properties of PP/a‐MWNT/PP‐g‐MA composite fibers were registered with varying DR of the as‐spun fiber. Orientation factors of a‐MWNT and PP chains along the fiber axis were correlated with the higher tensile modulus and tensile strength of PP/a‐MWNT/PP‐g‐MA composite fiber of varying DR. Crystallization studies indicated the role of hetero‐nucleating action of a‐MWNT in PP/a‐MWNT/PP‐g‐MA composite fiber. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pen.22186</doi><tpages>12</tpages></addata></record> |
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| ispartof | Polymer engineering and science, 2012-06, Vol.52 (6), p.1183-1194 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Amines Applied sciences Chemical processes Chemical properties Composite materials Composition Crystallization Exact sciences and technology Identification and classification Nanotubes Physicochemistry of polymers Polymer industry, paints, wood Polypropylene Polypropylene fibers Production processes Spectrum analysis Technology of polymers Tensile strength |
| title | Structure-property relationship studies in amine functionalized multiwall carbon nanotubes filled polypropylene composite fiber |
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