New Polyurethane Nanocomposites Based on Soya Oil

New polyurethane (PU) nanocomposites were prepared from a dispersion of 0 - 5% montmorillonite (MMT) clay with isocyanate and soya oil polyol that was synthesized via transesterification of triglycerides to reduce petroleum dependence. FT-IR spectra indicate the presence of hydrogen bonding between...

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Veröffentlicht in:Journal of Oleo Science 2014, Vol.63(2), pp.193-200
Hauptverfasser: Mohammed, Issam Ahmed, Khadir, Nurul Khizrien Abd, Al-Mulla, Emad Abbas Jaffar
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Sprache:eng
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Zusammenfassung:New polyurethane (PU) nanocomposites were prepared from a dispersion of 0 - 5% montmorillonite (MMT) clay with isocyanate and soya oil polyol that was synthesized via transesterification of triglycerides to reduce petroleum dependence. FT-IR spectra indicate the presence of hydrogen bonding between nanoclay and the polymer matrix, whereas the exfoliated structure of clay layers was confirmed by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Optical microscopy, mechanical and thermal analyses were done to investigate significant improvement of the nanocomposites. The results showed PU–3% nanoclay (NC) showed optimum results in mechanical properties such as tensile and flexural strength but the lowest in impact strength.
ISSN:1345-8957
1347-3352
DOI:10.5650/jos.ess13099