Pulse Radiolysis Study on a Highly Sensitive Chlorinated Resist ZEP520A

ZEP520A is one of the most popular positive electron beam (EB) resists used in research and photomask fabrication owing to its good spatial resolution, high sensitivity, and high dry etching resistance. Herein, EB-induced early reactions of ZEP520A were investigated via pulse radiolysis. Dissociativ...

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Veröffentlicht in:Journal of Photopolymer Science and Technology 2013/12/28, Vol.26(6), pp.745-750
Hauptverfasser: Hosaka, Yuji, Oyama, Tomoko Gowa, Oshima, Akihiro, Enomoto, Satoshi, Washio, Masakazu, Tagawa, Seiichi
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container_end_page 750
container_issue 6
container_start_page 745
container_title Journal of Photopolymer Science and Technology
container_volume 26
creator Hosaka, Yuji
Oyama, Tomoko Gowa
Oshima, Akihiro
Enomoto, Satoshi
Washio, Masakazu
Tagawa, Seiichi
description ZEP520A is one of the most popular positive electron beam (EB) resists used in research and photomask fabrication owing to its good spatial resolution, high sensitivity, and high dry etching resistance. Herein, EB-induced early reactions of ZEP520A were investigated via pulse radiolysis. Dissociative electron attachment and formation of a charge transfer complex were definitive contributing factors to the efficient degradation of ZEP520A. Furthermore, products induced by direct ionization of ZEP520A were observed in a highly concentrated ZEP520A solution in tetrahydrofuran, suggesting that early reactions in the ZEP520A solid film that were induced only by direct ionization could be simulated during pulse radiolysis in specific solutions.
doi_str_mv 10.2494/photopolymer.26.745
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subjects direct ionization
electron beam resist
pulse radiolysis
ZEP520A
title Pulse Radiolysis Study on a Highly Sensitive Chlorinated Resist ZEP520A
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