Development of the Fe Anodic Catalyst for Solid Oxide Fuel Cell Operated at Intermediate-temperature Direct Utilizing of Dimethylether Fuel
The Fe, Ni-BaCe0.8Y0.2O3−δ, and Pt catalysts and Pt catalysts were used as the anodic materials of an intermediate-temperature Solid Oxide Fuel Cell (SOFC) for direct utilization of dimethylether (DME) gas fuel. A proton conducting oxide BaCe0.8Y0.2O3−δ (BCY20) was used as the electrolyte (thickness...
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| Veröffentlicht in: | Denki kagaku oyobi kōgyō butsuri kagaku 2009/03/05, Vol.77(3), pp.225-228 |
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| container_title | Denki kagaku oyobi kōgyō butsuri kagaku |
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| creator | ISHIDA, Yousuke TAI, Ryosuke UI, Koichi TAKEUCHI, Ken FUJIMOTO, Kenjiro ITO, Shigeru |
| description | The Fe, Ni-BaCe0.8Y0.2O3−δ, and Pt catalysts and Pt catalysts were used as the anodic materials of an intermediate-temperature Solid Oxide Fuel Cell (SOFC) for direct utilization of dimethylether (DME) gas fuel. A proton conducting oxide BaCe0.8Y0.2O3−δ (BCY20) was used as the electrolyte (thickness 500 µm) and a Pt was used as the cathode. The cell was operated at 600°C. The maximum power density of the cell with the Fe anodic catalyst was 36.4 mW cm−2 at 70 mA cm−2, while the maximum power density of the cell with a Ni-BCY20 and the Pt anode were 5.5 mW cm−2 at 10 mA cm−2 and 8.4 mW cm−2 at 20 mA cm−2, respectively. DME was mainly decomposed to H2, CO and CH4 by Fe anode. In this study, we investigated the process of anodic reactions with H2 and CO fuel. |
| doi_str_mv | 10.5796/electrochemistry.77.225 |
| format | Article |
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A proton conducting oxide BaCe0.8Y0.2O3−δ (BCY20) was used as the electrolyte (thickness 500 µm) and a Pt was used as the cathode. The cell was operated at 600°C. The maximum power density of the cell with the Fe anodic catalyst was 36.4 mW cm−2 at 70 mA cm−2, while the maximum power density of the cell with a Ni-BCY20 and the Pt anode were 5.5 mW cm−2 at 10 mA cm−2 and 8.4 mW cm−2 at 20 mA cm−2, respectively. DME was mainly decomposed to H2, CO and CH4 by Fe anode. 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A proton conducting oxide BaCe0.8Y0.2O3−δ (BCY20) was used as the electrolyte (thickness 500 µm) and a Pt was used as the cathode. The cell was operated at 600°C. The maximum power density of the cell with the Fe anodic catalyst was 36.4 mW cm−2 at 70 mA cm−2, while the maximum power density of the cell with a Ni-BCY20 and the Pt anode were 5.5 mW cm−2 at 10 mA cm−2 and 8.4 mW cm−2 at 20 mA cm−2, respectively. DME was mainly decomposed to H2, CO and CH4 by Fe anode. In this study, we investigated the process of anodic reactions with H2 and CO fuel.</description><subject>Anode</subject><subject>Dimethylether (DME)</subject><subject>Proton Conducting Oxide</subject><subject>SOFC</subject><issn>1344-3542</issn><issn>2186-2451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNptkM9OGzEQxi3USkTAM9RSz5v67zp7REmhSJFyAM6W154ljrzr1Haqpq_AS2NIxQFxmZFmvt98ow-hb5TMperaHxDAlhTtFkafSzrOlZozJs_QjNFF2zAh6Rc0o1yIhkvBztFVzjtCCCVd27Fuhp5X8AdC3I8wFRwHXLaAbwBfT9F5i5emmHDMBQ8x4fsYvMObv95VyQECXkIIeLOHZAo4bAq-mwqkEZyvg6bA-LY6JMArn-qf-LH44P_56enVaeVHKNtjqAXS28FL9HUwIcPV_36BHm9-Pix_NevN7d3yet1YQXhpqCKKWON6DmIhjZBMDtyB5B0QSWmr2p4MPSd0sJ1sZcuEk85Az3pqeqU4v0DfT3f3Kf4-QC56Fw9pqpaaCqUEXUiuqkqdVDbFnBMMep_8aNJRU6Jfw9cfw9dK6Rp-JdcncpeLeYJ3zqTibYBPOX4qFX-X2a1JGib-Atr3m98</recordid><startdate>20090301</startdate><enddate>20090301</enddate><creator>ISHIDA, Yousuke</creator><creator>TAI, Ryosuke</creator><creator>UI, Koichi</creator><creator>TAKEUCHI, Ken</creator><creator>FUJIMOTO, Kenjiro</creator><creator>ITO, Shigeru</creator><general>The Electrochemical Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QL</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20090301</creationdate><title>Development of the Fe Anodic Catalyst for Solid Oxide Fuel Cell Operated at Intermediate-temperature Direct Utilizing of Dimethylether Fuel</title><author>ISHIDA, Yousuke ; 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A proton conducting oxide BaCe0.8Y0.2O3−δ (BCY20) was used as the electrolyte (thickness 500 µm) and a Pt was used as the cathode. The cell was operated at 600°C. The maximum power density of the cell with the Fe anodic catalyst was 36.4 mW cm−2 at 70 mA cm−2, while the maximum power density of the cell with a Ni-BCY20 and the Pt anode were 5.5 mW cm−2 at 10 mA cm−2 and 8.4 mW cm−2 at 20 mA cm−2, respectively. DME was mainly decomposed to H2, CO and CH4 by Fe anode. In this study, we investigated the process of anodic reactions with H2 and CO fuel.</abstract><cop>Tokyo</cop><pub>The Electrochemical Society of Japan</pub><doi>10.5796/electrochemistry.77.225</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Electrochemistry, 2009/03/05, Vol.77(3), pp.225-228 |
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| language | eng ; jpn |
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| source | J-STAGE Free; EZB-FREE-00999 freely available EZB journals |
| subjects | Anode Dimethylether (DME) Proton Conducting Oxide SOFC |
| title | Development of the Fe Anodic Catalyst for Solid Oxide Fuel Cell Operated at Intermediate-temperature Direct Utilizing of Dimethylether Fuel |
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