Organic Paramagnetic Ionic Liquids Based on Anion Containing 2,2,6,6-Tetramethyl-1-piperidinyloxyl Radical Moiety

Organic Paramagnetic Ionic Liquids Based on Anion Containing 2,2,6,6-Tetramethyl-1-piperidinyloxyl Radical Moiety

A series of genuine organic paramagnetic ionic liquids were prepared utilizing 2,2,6,6-tetramethyl-1-piperidinyloxyl-4-sulfate (TEMPO-OSO3) anion with S=1⁄2 radical spin. Their static susceptibilities and EPR spectra can be explained in terms of the paramagnetic spins on the TEMPO radical moieties,...

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Veröffentlicht in:Chemistry letters 2007-09, Vol.36 (9), p.1096-1097
Hauptverfasser: Yoshida, Yukihiro, Tanaka, Hirofusa, Saito, Gunzi
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container_title Chemistry letters
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creator Yoshida, Yukihiro
Tanaka, Hirofusa
Saito, Gunzi
description A series of genuine organic paramagnetic ionic liquids were prepared utilizing 2,2,6,6-tetramethyl-1-piperidinyloxyl-4-sulfate (TEMPO-OSO3) anion with S=1⁄2 radical spin. Their static susceptibilities and EPR spectra can be explained in terms of the paramagnetic spins on the TEMPO radical moieties, although they have much low fluidities and ionic conductivities.
doi_str_mv 10.1246/cl.2007.1096
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title Organic Paramagnetic Ionic Liquids Based on Anion Containing 2,2,6,6-Tetramethyl-1-piperidinyloxyl Radical Moiety
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