Synthesis of CF3-Substituted Olefins by Julia-Kocienski Olefination Using 2-[(2,2,2-Trifluoroethyl)sulfonyl]benzo[d]thiazole as Trifluoromethylation Agent

A modified Julia–Kocienski protocol was investigated for the synthesis of CF3‐substituted terminal olefins. By employing a simple one‐step procedure, aldehydes were converted into the corresponding CF3‐substituted olefins using 2‐[(2,2,2‐trifluoroethyl)sulfonyl]benzo[d]thiazole as the trifluoromethy...

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Veröffentlicht in:	European journal of organic chemistry 2013-12, Vol.2013 (35), p.7996-8003
Hauptverfasser:	Hafner, Andreas, Fischer, Tobias S., Bräse, Stefan
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Fluorine Olefination Sulfur Synthetic methods
Online-Zugang:	Volltext
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