Copper-Catalyzed Aromatic CH Bond Cyanation by CCN Bond Cleavage of Inert Acetonitrile

Cut and paste! A Cu-catalyzed aromatic CH cyanation with acetonitrile as the nitrile source by CCN cleavage has been developed (see scheme; TMEDA=N,N,N',N'-tetramethylethylenediamine). The reaction is catalytic in copper, and it is found that using (Me3 Si)2 as an additive plays a critical...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2013-12, Vol.19 (50), p.16880
Hauptverfasser:	Kou, Xuezhen, Zhao, Mengdi, Qiao, Xixue, Zhu, Yamin, Tong, Xiaofeng, Shen, Zengming
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!