Copper-Catalyzed Aromatic CH Bond Cyanation by CCN Bond Cleavage of Inert Acetonitrile

Copper-Catalyzed Aromatic CH Bond Cyanation by CCN Bond Cleavage of Inert Acetonitrile

Cut and paste! A Cu-catalyzed aromatic CH cyanation with acetonitrile as the nitrile source by CCN cleavage has been developed (see scheme; TMEDA=N,N,N',N'-tetramethylethylenediamine). The reaction is catalytic in copper, and it is found that using (Me3 Si)2 as an additive plays a critical...

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Veröffentlicht in:Chemistry : a European journal 2013-12, Vol.19 (50), p.16880
Hauptverfasser: Kou, Xuezhen, Zhao, Mengdi, Qiao, Xixue, Zhu, Yamin, Tong, Xiaofeng, Shen, Zengming
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container_end_page
container_issue 50
container_start_page 16880
container_title Chemistry : a European journal
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creator Kou, Xuezhen
Zhao, Mengdi
Qiao, Xixue
Zhu, Yamin
Tong, Xiaofeng
Shen, Zengming
description Cut and paste! A Cu-catalyzed aromatic CH cyanation with acetonitrile as the nitrile source by CCN cleavage has been developed (see scheme; TMEDA=N,N,N',N'-tetramethylethylenediamine). The reaction is catalytic in copper, and it is found that using (Me3 Si)2 as an additive plays a critical role in promoting CCN cleavage and enhancing the reaction rate.
doi_str_mv 10.1002/chem.201303637
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title Copper-Catalyzed Aromatic CH Bond Cyanation by CCN Bond Cleavage of Inert Acetonitrile
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