Importance of the Order of Successive Catalyst-transfer Condensation Polymerization in the Synthesis of Block Copolymers of Polythiophene and Poly(p-phenylene)

Importance of the Order of Successive Catalyst-transfer Condensation Polymerization in the Synthesis of Block Copolymers of Polythiophene and Poly(p-phenylene)

Successive catalyst-transfer condensation polymerization of a Grignard-type phenylene monomer and then a thiophene monomer with a Ni catalyst yields well-defined block copolymers of poly(p-phenylene) and polythiophene, but the reverse order of polymerization results in polymers with broad molecular...

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Veröffentlicht in:Chemistry letters 2008-10, Vol.37 (10), p.1022-1023
Hauptverfasser: Miyakoshi, Ryo, Yokoyama, Akihiro, Yokozawa, Tsutomu
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container_end_page 1023
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container_title Chemistry letters
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creator Miyakoshi, Ryo
Yokoyama, Akihiro
Yokozawa, Tsutomu
description Successive catalyst-transfer condensation polymerization of a Grignard-type phenylene monomer and then a thiophene monomer with a Ni catalyst yields well-defined block copolymers of poly(p-phenylene) and polythiophene, but the reverse order of polymerization results in polymers with broad molecular weight distribution.
doi_str_mv 10.1246/cl.2008.1022
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title Importance of the Order of Successive Catalyst-transfer Condensation Polymerization in the Synthesis of Block Copolymers of Polythiophene and Poly(p-phenylene)
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