Site- and Stereoselectivity in the Photochemical Oxetane Formation Reaction (Paternò-Büchi Reaction) of Tetrahydrobenzofuranols with Benzophenone

Site- and Stereoselectivity in the Photochemical Oxetane Formation Reaction (Paternò-Büchi Reaction) of Tetrahydrobenzofuranols with Benzophenone

The Paternò-Büchi reactions of tetrahydrobenzofuranols with benzophenone were investigated to reveal site- and stereoselectivity in oxetane formation reactions. Both selectivities were found to be largely dependent on the reaction temperature. The trans selectivity increased with a decrease in tempe...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2008-08, Vol.37 (8), p.822
Hauptverfasser: Yabuno, Youhei, Hiraga, Yoshikazu, Abe, Manabu
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue 8
container_start_page 822
container_title Chemistry letters
container_volume 37
creator Yabuno, Youhei
Hiraga, Yoshikazu
Abe, Manabu
description The Paternò-Büchi reactions of tetrahydrobenzofuranols with benzophenone were investigated to reveal site- and stereoselectivity in oxetane formation reactions. Both selectivities were found to be largely dependent on the reaction temperature. The trans selectivity increased with a decrease in temperature, and the more-substituted oxetanes were selectively formed at high temperature.
format Article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_1461011494</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3135401261</sourcerecordid><originalsourceid>FETCH-proquest_journals_14610114943</originalsourceid><addsrcrecordid>eNqNjD1OAzEQhS0EEsvPHUaigcKSvbtskjaIiI6IpI-MMys72swEexYI1-Am1HS5GAEhaqr36X1P70AVtqqH2gzs9aEqTNU0emDK8lid5LwyxgxHVVmo91kU1OBoCTPBhJyxQy_xOcoWIoEEhGlgYR9wHb3r4P4VxRHChNPaSWSCB3T-By6nbv9Buw893n36EP_MFXALc5TkwnaZ-BHpjds-OeIuw0uUAOPvahOQmPBMHbWuy3j-m6fqYnI7v7nTm8RPPWZZrLhPtFcLWzfWWFuP6up_qy9tIFsw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1461011494</pqid></control><display><type>article</type><title>Site- and Stereoselectivity in the Photochemical Oxetane Formation Reaction (Paternò-Büchi Reaction) of Tetrahydrobenzofuranols with Benzophenone</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Yabuno, Youhei ; Hiraga, Yoshikazu ; Abe, Manabu</creator><creatorcontrib>Yabuno, Youhei ; Hiraga, Yoshikazu ; Abe, Manabu</creatorcontrib><description>The Paternò-Büchi reactions of tetrahydrobenzofuranols with benzophenone were investigated to reveal site- and stereoselectivity in oxetane formation reactions. Both selectivities were found to be largely dependent on the reaction temperature. The trans selectivity increased with a decrease in temperature, and the more-substituted oxetanes were selectively formed at high temperature.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><language>eng</language><publisher>Tokyo: Chemical Society of Japan</publisher><ispartof>Chemistry letters, 2008-08, Vol.37 (8), p.822</ispartof><rights>Copyright Japan Science and Technology Agency 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780</link.rule.ids></links><search><creatorcontrib>Yabuno, Youhei</creatorcontrib><creatorcontrib>Hiraga, Yoshikazu</creatorcontrib><creatorcontrib>Abe, Manabu</creatorcontrib><title>Site- and Stereoselectivity in the Photochemical Oxetane Formation Reaction (Paternò-Büchi Reaction) of Tetrahydrobenzofuranols with Benzophenone</title><title>Chemistry letters</title><description>The Paternò-Büchi reactions of tetrahydrobenzofuranols with benzophenone were investigated to reveal site- and stereoselectivity in oxetane formation reactions. Both selectivities were found to be largely dependent on the reaction temperature. The trans selectivity increased with a decrease in temperature, and the more-substituted oxetanes were selectively formed at high temperature.</description><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqNjD1OAzEQhS0EEsvPHUaigcKSvbtskjaIiI6IpI-MMys72swEexYI1-Am1HS5GAEhaqr36X1P70AVtqqH2gzs9aEqTNU0emDK8lid5LwyxgxHVVmo91kU1OBoCTPBhJyxQy_xOcoWIoEEhGlgYR9wHb3r4P4VxRHChNPaSWSCB3T-By6nbv9Buw893n36EP_MFXALc5TkwnaZ-BHpjds-OeIuw0uUAOPvahOQmPBMHbWuy3j-m6fqYnI7v7nTm8RPPWZZrLhPtFcLWzfWWFuP6up_qy9tIFsw</recordid><startdate>20080801</startdate><enddate>20080801</enddate><creator>Yabuno, Youhei</creator><creator>Hiraga, Yoshikazu</creator><creator>Abe, Manabu</creator><general>Chemical Society of Japan</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20080801</creationdate><title>Site- and Stereoselectivity in the Photochemical Oxetane Formation Reaction (Paternò-Büchi Reaction) of Tetrahydrobenzofuranols with Benzophenone</title><author>Yabuno, Youhei ; Hiraga, Yoshikazu ; Abe, Manabu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_journals_14610114943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yabuno, Youhei</creatorcontrib><creatorcontrib>Hiraga, Yoshikazu</creatorcontrib><creatorcontrib>Abe, Manabu</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yabuno, Youhei</au><au>Hiraga, Yoshikazu</au><au>Abe, Manabu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Site- and Stereoselectivity in the Photochemical Oxetane Formation Reaction (Paternò-Büchi Reaction) of Tetrahydrobenzofuranols with Benzophenone</atitle><jtitle>Chemistry letters</jtitle><date>2008-08-01</date><risdate>2008</risdate><volume>37</volume><issue>8</issue><spage>822</spage><pages>822-</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>The Paternò-Büchi reactions of tetrahydrobenzofuranols with benzophenone were investigated to reveal site- and stereoselectivity in oxetane formation reactions. Both selectivities were found to be largely dependent on the reaction temperature. The trans selectivity increased with a decrease in temperature, and the more-substituted oxetanes were selectively formed at high temperature.</abstract><cop>Tokyo</cop><pub>Chemical Society of Japan</pub></addata></record>
fulltext fulltext
identifier ISSN: 0366-7022
ispartof Chemistry letters, 2008-08, Vol.37 (8), p.822
issn 0366-7022
1348-0715
language eng
recordid cdi_proquest_journals_1461011494
source Oxford University Press Journals All Titles (1996-Current)
title Site- and Stereoselectivity in the Photochemical Oxetane Formation Reaction (Paternò-Büchi Reaction) of Tetrahydrobenzofuranols with Benzophenone
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-06T03%3A04%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Site-%20and%20Stereoselectivity%20in%20the%20Photochemical%20Oxetane%20Formation%20Reaction%20(Patern%C3%B2-B%C3%BCchi%20Reaction)%20of%20Tetrahydrobenzofuranols%20with%20Benzophenone&rft.jtitle=Chemistry%20letters&rft.au=Yabuno,%20Youhei&rft.date=2008-08-01&rft.volume=37&rft.issue=8&rft.spage=822&rft.pages=822-&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/&rft_dat=%3Cproquest%3E3135401261%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1461011494&rft_id=info:pmid/&rfr_iscdi=true