Alkyl Phosphinites
Recent advances in the oxidation-reduction condensation reaction of alkyl phosphinites are described. The carbon-sulfur, carbon-carbon, or carbon-nitrogen bond forming reactions and cyanation, isocyanation reactions are established. These reactions proceed through inversion of configuration even whe...
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| Veröffentlicht in: | Chemistry letters 2007-01, Vol.36 (1), p.2 |
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| container_title | Chemistry letters |
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| creator | Mukaiyama, Teruaki Yamabe, Hokuto |
| description | Recent advances in the oxidation-reduction condensation reaction of alkyl phosphinites are described. The carbon-sulfur, carbon-carbon, or carbon-nitrogen bond forming reactions and cyanation, isocyanation reactions are established. These reactions proceed through inversion of configuration even when tertiary alkyl phosphinites are employed, providing thus, a novel route to chiral hydrosulfides, amines, nitriles, and isocyanides from easily available chiral alcohols. |
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| identifier | ISSN: 0366-7022 |
| ispartof | Chemistry letters, 2007-01, Vol.36 (1), p.2 |
| issn | 0366-7022 1348-0715 |
| language | eng |
| recordid | cdi_proquest_journals_1461008893 |
| source | Oxford University Press Journals All Titles (1996-Current) |
| title | Alkyl Phosphinites |
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