Enantioselective Recognition of Calix[5]arene-based Artificial Receptor Bearing Chiral Macrocycle for Chiral Ethyltrimethylammonium Salts

Enantioselective Recognition of Calix[5]arene-based Artificial Receptor Bearing Chiral Macrocycle for Chiral Ethyltrimethylammonium Salts

Calix[5]arene-based artificial receptor 1 capped with chiral macrocycle 4 was synthesized and showed strong binding toward ethyltrimethylammonium salts via cation/π and hydrogen-bonding interactions. The calix[5]arene cavity provided the dissymmetric guest-binding environment in which chiral guests...

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Veröffentlicht in:Chemistry letters 2007-08, Vol.36 (8), p.1054-1055
Hauptverfasser: Haino, Takeharu, Fukuoka, Hiroyuki, Katayama, Masakazu, Fukazawa, Yoshimasa
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container_issue 8
container_start_page 1054
container_title Chemistry letters
container_volume 36
creator Haino, Takeharu
Fukuoka, Hiroyuki
Katayama, Masakazu
Fukazawa, Yoshimasa
description Calix[5]arene-based artificial receptor 1 capped with chiral macrocycle 4 was synthesized and showed strong binding toward ethyltrimethylammonium salts via cation/π and hydrogen-bonding interactions. The calix[5]arene cavity provided the dissymmetric guest-binding environment in which chiral guests 6–14 were encapsulated in an enantioselective fashion.
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title Enantioselective Recognition of Calix[5]arene-based Artificial Receptor Bearing Chiral Macrocycle for Chiral Ethyltrimethylammonium Salts
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