Porous Magnets Based on Copper–Octacyanotungsten Containing Noncoordinated Alcohol Molecules

Porous Magnets Based on Copper–Octacyanotungsten Containing Noncoordinated Alcohol Molecules

Two types of molecule-based magnets CuII3[WV(CN)8]2(pyrimidine)2·2-propanol·6H2O (1) and CuII3[WV(CN)8]2(pyrimidine)2·1-butanol·5H2O (2) are prepared. These compounds have a 3-dimensional porous structure, in which a noncoordinated 2-propanol or 1-butanol molecule is penetrated. These compounds show...

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Veröffentlicht in:Chemistry letters 2007-12, Vol.36 (12), p.1464-1465
Hauptverfasser: Tsunobuchi, Yoshihide, Hashimoto, Kazuhito, Shiro, Motoo, Hozumi, Toshiya, Ohkoshi, Shin-ichi
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container_end_page 1465
container_issue 12
container_start_page 1464
container_title Chemistry letters
container_volume 36
creator Tsunobuchi, Yoshihide
Hashimoto, Kazuhito
Shiro, Motoo
Hozumi, Toshiya
Ohkoshi, Shin-ichi
description Two types of molecule-based magnets CuII3[WV(CN)8]2(pyrimidine)2·2-propanol·6H2O (1) and CuII3[WV(CN)8]2(pyrimidine)2·1-butanol·5H2O (2) are prepared. These compounds have a 3-dimensional porous structure, in which a noncoordinated 2-propanol or 1-butanol molecule is penetrated. These compounds show long-range magnetic ordering with Curie temperatures of 8.2 K (1) and 8.4 K (2) although large organic molecules are packed.
doi_str_mv 10.1246/cl.2007.1464
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title Porous Magnets Based on Copper–Octacyanotungsten Containing Noncoordinated Alcohol Molecules
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