Kinetic Study of Dehydrogenation between H–Siloxane and Ti–OH on TiO2

Kinetic Study of Dehydrogenation between H–Siloxane and Ti–OH on TiO2

The kinetics of the solid–liquid reaction between titanium dioxide (TiO2) and H–siloxane was investigated. The solid–liquid reaction involved two dehydrogenation condensations; one between free Ti–OH groups and Si–H groups, and another between hydrated Ti–OH groups and Si–H groups. The reactivity of...

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Veröffentlicht in:Chemistry letters 2005-04, Vol.34 (4), p.460-461
Hauptverfasser: Nakabayashi, Akira, Kondo, Junko N, Hara, Michikazu, Domen, Kazunari
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container_title Chemistry letters
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creator Nakabayashi, Akira
Kondo, Junko N
Hara, Michikazu
Domen, Kazunari
description The kinetics of the solid–liquid reaction between titanium dioxide (TiO2) and H–siloxane was investigated. The solid–liquid reaction involved two dehydrogenation condensations; one between free Ti–OH groups and Si–H groups, and another between hydrated Ti–OH groups and Si–H groups. The reactivity of the Ti–OH group is considered to be restricted by hydrogen bonding with a molecule containing an OH group, such as water or alcohol.
doi_str_mv 10.1246/cl.2005.460
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source Oxford University Press Journals All Titles (1996-Current)
title Kinetic Study of Dehydrogenation between H–Siloxane and Ti–OH on TiO2
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