Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System

Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System

Alkane was efficiently oxidized to alcohol and ketone with O2 and H2 by EuCl3–TiO(acac)2–Pt/SiO2 catalytic system with very high H2-utilization efficiencies, 75% for adamantane and 60% for cyclohexane oxidations. ESR studies suggested that electrons originated in H2 effectively conducted to O2 throu...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2005-11, Vol.34 (11), p.1486-1487
Hauptverfasser: Yamanaka, Ichiro, Gomi, Toshikazu, Nabeta, Takashi, Otsuka, Kiyoshi
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1487
container_issue 11
container_start_page 1486
container_title Chemistry letters
container_volume 34
creator Yamanaka, Ichiro
Gomi, Toshikazu
Nabeta, Takashi
Otsuka, Kiyoshi
description Alkane was efficiently oxidized to alcohol and ketone with O2 and H2 by EuCl3–TiO(acac)2–Pt/SiO2 catalytic system with very high H2-utilization efficiencies, 75% for adamantane and 60% for cyclohexane oxidations. ESR studies suggested that electrons originated in H2 effectively conducted to O2 through Pt, Eu3+/Eu2+, and Ti4+/Ti3+. Eu2+ and Ti3+ species reductively activated O2, generating active oxygen species.
doi_str_mv 10.1246/cl.2005.1486
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1460994972</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3135362651</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1582-8b3dac4506a4eb43f6ba312c35c4c66696a13d4689a621f153b8ee96aa4301f63</originalsourceid><addsrcrecordid>eNptkM1Kw0AURgdRsFZ3PsCAWxPnL9PJspRqhUoF63q4mczQqWlSkymane_gG_okTmkXLtzcC5dzvw8OQteUpJQJeWeqlBGSpVQoeYIGlAuVkBHNTtGAcCmTEWHsHF103ZoQonLOBuhp6pw33tYBLz59CcE3NW4cHldvUFv84cMKLxiGusQzhoseT3c_X99LH8dzwBMIUPXBG_zSd8FuLtGZg6qzV8c9RK_30-VklswXD4-T8TwxNFMsUQUvwYiMSBC2ENzJAjhlhmdGGCllLoHyUkiVg2TU0YwXytp4BcEJdZIP0c0hd9s27zvbBb1udm0dKzUVkuS5yEcsUrcHyrRN17XW6W3rN9D2mhK9F6ZNpffC9F5YxPMjvrIbb2JYE8WEfg1bqP8U_Pf7C7ZqcK0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1460994972</pqid></control><display><type>article</type><title>Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Yamanaka, Ichiro ; Gomi, Toshikazu ; Nabeta, Takashi ; Otsuka, Kiyoshi</creator><creatorcontrib>Yamanaka, Ichiro ; Gomi, Toshikazu ; Nabeta, Takashi ; Otsuka, Kiyoshi</creatorcontrib><description>Alkane was efficiently oxidized to alcohol and ketone with O2 and H2 by EuCl3–TiO(acac)2–Pt/SiO2 catalytic system with very high H2-utilization efficiencies, 75% for adamantane and 60% for cyclohexane oxidations. ESR studies suggested that electrons originated in H2 effectively conducted to O2 through Pt, Eu3+/Eu2+, and Ti4+/Ti3+. Eu2+ and Ti3+ species reductively activated O2, generating active oxygen species.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.2005.1486</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><ispartof>Chemistry letters, 2005-11, Vol.34 (11), p.1486-1487</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2005</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1582-8b3dac4506a4eb43f6ba312c35c4c66696a13d4689a621f153b8ee96aa4301f63</citedby><cites>FETCH-LOGICAL-c1582-8b3dac4506a4eb43f6ba312c35c4c66696a13d4689a621f153b8ee96aa4301f63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Yamanaka, Ichiro</creatorcontrib><creatorcontrib>Gomi, Toshikazu</creatorcontrib><creatorcontrib>Nabeta, Takashi</creatorcontrib><creatorcontrib>Otsuka, Kiyoshi</creatorcontrib><title>Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>Alkane was efficiently oxidized to alcohol and ketone with O2 and H2 by EuCl3–TiO(acac)2–Pt/SiO2 catalytic system with very high H2-utilization efficiencies, 75% for adamantane and 60% for cyclohexane oxidations. ESR studies suggested that electrons originated in H2 effectively conducted to O2 through Pt, Eu3+/Eu2+, and Ti4+/Ti3+. Eu2+ and Ti3+ species reductively activated O2, generating active oxygen species.</description><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNptkM1Kw0AURgdRsFZ3PsCAWxPnL9PJspRqhUoF63q4mczQqWlSkymane_gG_okTmkXLtzcC5dzvw8OQteUpJQJeWeqlBGSpVQoeYIGlAuVkBHNTtGAcCmTEWHsHF103ZoQonLOBuhp6pw33tYBLz59CcE3NW4cHldvUFv84cMKLxiGusQzhoseT3c_X99LH8dzwBMIUPXBG_zSd8FuLtGZg6qzV8c9RK_30-VklswXD4-T8TwxNFMsUQUvwYiMSBC2ENzJAjhlhmdGGCllLoHyUkiVg2TU0YwXytp4BcEJdZIP0c0hd9s27zvbBb1udm0dKzUVkuS5yEcsUrcHyrRN17XW6W3rN9D2mhK9F6ZNpffC9F5YxPMjvrIbb2JYE8WEfg1bqP8U_Pf7C7ZqcK0</recordid><startdate>200511</startdate><enddate>200511</enddate><creator>Yamanaka, Ichiro</creator><creator>Gomi, Toshikazu</creator><creator>Nabeta, Takashi</creator><creator>Otsuka, Kiyoshi</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200511</creationdate><title>Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System</title><author>Yamanaka, Ichiro ; Gomi, Toshikazu ; Nabeta, Takashi ; Otsuka, Kiyoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1582-8b3dac4506a4eb43f6ba312c35c4c66696a13d4689a621f153b8ee96aa4301f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yamanaka, Ichiro</creatorcontrib><creatorcontrib>Gomi, Toshikazu</creatorcontrib><creatorcontrib>Nabeta, Takashi</creatorcontrib><creatorcontrib>Otsuka, Kiyoshi</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yamanaka, Ichiro</au><au>Gomi, Toshikazu</au><au>Nabeta, Takashi</au><au>Otsuka, Kiyoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2005-11</date><risdate>2005</risdate><volume>34</volume><issue>11</issue><spage>1486</spage><epage>1487</epage><pages>1486-1487</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Alkane was efficiently oxidized to alcohol and ketone with O2 and H2 by EuCl3–TiO(acac)2–Pt/SiO2 catalytic system with very high H2-utilization efficiencies, 75% for adamantane and 60% for cyclohexane oxidations. ESR studies suggested that electrons originated in H2 effectively conducted to O2 through Pt, Eu3+/Eu2+, and Ti4+/Ti3+. Eu2+ and Ti3+ species reductively activated O2, generating active oxygen species.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.2005.1486</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0366-7022
ispartof Chemistry letters, 2005-11, Vol.34 (11), p.1486-1487
issn 0366-7022
1348-0715
language eng
recordid cdi_proquest_journals_1460994972
source Oxford University Press Journals All Titles (1996-Current)
title Efficient Oxidation of Alkane with O2 and H2 by Eu–Ti–Pt Catalytic System
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T06%3A24%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Efficient%20Oxidation%20of%20Alkane%20with%20O2%20and%20H2%20by%20Eu%E2%80%93Ti%E2%80%93Pt%20Catalytic%20System&rft.jtitle=Chemistry%20letters&rft.au=Yamanaka,%20Ichiro&rft.date=2005-11&rft.volume=34&rft.issue=11&rft.spage=1486&rft.epage=1487&rft.pages=1486-1487&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1246/cl.2005.1486&rft_dat=%3Cproquest_cross%3E3135362651%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1460994972&rft_id=info:pmid/&rfr_iscdi=true