Highly Anomer- and Regio-selective Transesterification Catalyzed by Alkaline Protease from Bacillus subtilis in Organic Media

Highly Anomer- and Regio-selective Transesterification Catalyzed by Alkaline Protease from Bacillus subtilis in Organic Media

Highly anomer-selective-6(6′)-acylation reactions from anomeric mixtures of several mono- and disaccharides with divinyl dicarboxylates ranging from 4 to 10 carbon atoms were catalyzed by an alkaline protease from Bacillus subtilis in pyridine. A series of new pure α-anomeric polymerisable vinyl sug...

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Veröffentlicht in:Chemistry letters 2004-02, Vol.33 (2), p.94-95
Hauptverfasser: Wu, Qi, Lu, Deshui, Xiao, Yongmei, Yao, Shiping, Lin, Xianfu
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container_title Chemistry letters
container_volume 33
creator Wu, Qi
Lu, Deshui
Xiao, Yongmei
Yao, Shiping
Lin, Xianfu
description Highly anomer-selective-6(6′)-acylation reactions from anomeric mixtures of several mono- and disaccharides with divinyl dicarboxylates ranging from 4 to 10 carbon atoms were catalyzed by an alkaline protease from Bacillus subtilis in pyridine. A series of new pure α-anomeric polymerisable vinyl sugar esters of dibasic acids were synthesized in good selectivity and yields.
doi_str_mv 10.1246/cl.2004.94
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source Oxford University Press Journals All Titles (1996-Current)
title Highly Anomer- and Regio-selective Transesterification Catalyzed by Alkaline Protease from Bacillus subtilis in Organic Media
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