(Salen)ruthenium-catalyzed Desymmetrization of meso-Diols (2). Apical Ligand Effect on Enantioselectivity

Enantiotopos-selectivity of aerobic oxidation of meso-diols using chiral (nitrosyl)Ru(salen) complexes as catalyst was found to be dependent on the nature of their apical ligand. The oxidation with complex 5 possessing an apical hydroxo ligand as the catalyst showed moderate to good enantioselectivi...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry letters 2003-06, Vol.32 (6), p.480-481
Hauptverfasser:	Shimizu, Hideki, Katsuki, Tsutomu
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!