Selenothiophosphinic Acid Salts

Selenothiophosphinic Acid Salts

An efficient synthesis of selenothiophosphinic acid salts is achieved by reacting selenothiophosphinic acid S-(2-trimethylsilyl)ethyl esters with ammonium or alkali metal fluorides. The X-ray structure analysis of the potassium 18-crown-6 selenothiophosphinic acid salt shows that the salt is monomer...

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Veröffentlicht in:Chemistry letters 2002-09, Vol.31 (9), p.914
Hauptverfasser: Murai, Toshiaki, Kimura, Tsutomu, Miwa, Akihiro, Kurachi, Daisuke, Kato, Shinzi
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creator Murai, Toshiaki
Kimura, Tsutomu
Miwa, Akihiro
Kurachi, Daisuke
Kato, Shinzi
description An efficient synthesis of selenothiophosphinic acid salts is achieved by reacting selenothiophosphinic acid S-(2-trimethylsilyl)ethyl esters with ammonium or alkali metal fluorides. The X-ray structure analysis of the potassium 18-crown-6 selenothiophosphinic acid salt shows that the salt is monomeric. Alkylation of the salts proceeds at the selenium atom whereas acylation occurs at the sulfur atom.
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source Oxford University Press Journals All Titles (1996-Current)
title Selenothiophosphinic Acid Salts
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