Sulfenamide-catalyzed Oxidation of Primary and Secondary Alcohols with Molecular Bromine

Primary and secondary alcohols were smoothly oxidized to the corresponding aldehydes and ketones in high yields at room temperature with 1.1 equiv. of molecular bromine by using a catalytic amount of N-t-butyl-2-nitrobenzenesulfenamide in the coexistence of potassium carbonate and molecular sieves 4...

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Veröffentlicht in:Chemistry letters 2003-02, Vol.32 (2), p.182-183
Hauptverfasser: Matsuo, Jun-ichi, Kawana, Asahi, Yamanaka, Hiroyuki, Mukaiyama, Teruaki
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container_title Chemistry letters
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creator Matsuo, Jun-ichi
Kawana, Asahi
Yamanaka, Hiroyuki
Mukaiyama, Teruaki
description Primary and secondary alcohols were smoothly oxidized to the corresponding aldehydes and ketones in high yields at room temperature with 1.1 equiv. of molecular bromine by using a catalytic amount of N-t-butyl-2-nitrobenzenesulfenamide in the coexistence of potassium carbonate and molecular sieves 4A.
doi_str_mv 10.1246/cl.2003.182
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source Oxford University Press Journals All Titles (1996-Current)
title Sulfenamide-catalyzed Oxidation of Primary and Secondary Alcohols with Molecular Bromine
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