The Ruthenium-Catalyzed Addition of [beta] C-H Bonds in Aldehydes to Olefins

The Ruthenium-Catalyzed Addition of [beta] C-H Bonds in Aldehydes to Olefins

The addition of a β C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)2(CO)(PPh3)3 as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and t...

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Veröffentlicht in:Chemistry letters 2001-05, Vol.30 (5), p.386
Hauptverfasser: Kakiuchi, Fumitoshi, Sato, Taisuke, Igi, Kimitaka, Chatani, Naoto, Murai, Shinji
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container_issue 5
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container_title Chemistry letters
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creator Kakiuchi, Fumitoshi
Sato, Taisuke
Igi, Kimitaka
Chatani, Naoto
Murai, Shinji
description The addition of a β C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)2(CO)(PPh3)3 as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and the presence of an electron donating substituent appear to be important factor in accomplishing the desired coupling reaction.
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source Oxford University Press Journals All Titles (1996-Current)
title The Ruthenium-Catalyzed Addition of [beta] C-H Bonds in Aldehydes to Olefins
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