Synthesis of Novel Group 4 Metallocene-Containing Silsesquioxanes with a Vinyl Group

Synthesis of Novel Group 4 Metallocene-Containing Silsesquioxanes with a Vinyl Group

Novel zirconocene or hafnocene-containing silsesquioxanes with a vinyl group Cp2M{[(vinyl)Me2Si](c-C5H9)7Si7O12} (Cp = cyclopentadienyl, M = Zr, Hf) were synthesized, as well as a derivative with a trimethylsilyl group Cp2Zr[(Me3Si)(c-C5H9)7Si7O12]. A derivative containing a dimethylethoxysilyl grou...

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Veröffentlicht in:Chemistry letters 2000-06, Vol.29 (6), p.628-629
Hauptverfasser: Wada, Kenji, Bundo, Masaki, Nakabayashi, Daisuke, Itayama, Naohiko, Kondo, Teruyuki, Mitsudo, Take-aki
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container_end_page 629
container_issue 6
container_start_page 628
container_title Chemistry letters
container_volume 29
creator Wada, Kenji
Bundo, Masaki
Nakabayashi, Daisuke
Itayama, Naohiko
Kondo, Teruyuki
Mitsudo, Take-aki
description Novel zirconocene or hafnocene-containing silsesquioxanes with a vinyl group Cp2M{[(vinyl)Me2Si](c-C5H9)7Si7O12} (Cp = cyclopentadienyl, M = Zr, Hf) were synthesized, as well as a derivative with a trimethylsilyl group Cp2Zr[(Me3Si)(c-C5H9)7Si7O12]. A derivative containing a dimethylethoxysilyl group was also synthesized.
doi_str_mv 10.1246/cl.2000.628
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source Oxford University Press Journals All Titles (1996-Current)
title Synthesis of Novel Group 4 Metallocene-Containing Silsesquioxanes with a Vinyl Group
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