Linear Relationship of the Rate of Isobutene Formation from CO and H2 on ZrO2 to the Monoclinic Phase Fraction

Linear Relationship of the Rate of Isobutene Formation from CO and H2 on ZrO2 to the Monoclinic Phase Fraction

The rate of formation of isobutene from CO and H2 over ZrO2 is proportional to the volume fraction of the monoclinic phase. The active site was explained by both vacant site and stronger bascity due to the shorter Zr–O bond in the monoclinic structure.

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Veröffentlicht in:Chemistry letters 1999-07, Vol.28 (7), p.575-576
Hauptverfasser: Maruya, Ken-ichi, Komiya, Teruaki, Okumura, Koichiro, Yashima, Masatomo
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container_end_page 576
container_issue 7
container_start_page 575
container_title Chemistry letters
container_volume 28
creator Maruya, Ken-ichi
Komiya, Teruaki
Okumura, Koichiro
Yashima, Masatomo
description The rate of formation of isobutene from CO and H2 over ZrO2 is proportional to the volume fraction of the monoclinic phase. The active site was explained by both vacant site and stronger bascity due to the shorter Zr–O bond in the monoclinic structure.
doi_str_mv 10.1246/cl.1999.575
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source Oxford University Press Journals All Titles (1996-Current)
title Linear Relationship of the Rate of Isobutene Formation from CO and H2 on ZrO2 to the Monoclinic Phase Fraction
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