An in situ FT-IR Study on Photocatalytic Reaction at Semiconductor-Aqueous Solution Interface — Mechanism of Photocatalytic N-Cyclization of (S)-Lysine

An in situ FT-IR Study on Photocatalytic Reaction at Semiconductor-Aqueous Solution Interface — Mechanism of Photocatalytic N-Cyclization of (S)-Lysine

Photoinduced reaction occurring at an aqueous solution-semiconductor interface was analyzed in situ by reflection FT-IR spectroscopy. The photoinduced reflection spectral change, ΔR (= (R−R0)/R0), was recorded by using an IR cell consisting of a semiconductor (TiO2 or CdS) thin film electrode, a thi...

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Veröffentlicht in:Chemistry letters 1997-01, Vol.26 (1), p.91-92
Hauptverfasser: Ohtani, Bunsho, Yako, Takayuki, Samukawa, Yoriaki, Nishimoto, Sei-ichi, Kanamura, Kiyoshi
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container_title Chemistry letters
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creator Ohtani, Bunsho
Yako, Takayuki
Samukawa, Yoriaki
Nishimoto, Sei-ichi
Kanamura, Kiyoshi
description Photoinduced reaction occurring at an aqueous solution-semiconductor interface was analyzed in situ by reflection FT-IR spectroscopy. The photoinduced reflection spectral change, ΔR (= (R−R0)/R0), was recorded by using an IR cell consisting of a semiconductor (TiO2 or CdS) thin film electrode, a thin layer of aqueous (S)-lysine solution, and a calcium fluoride window. Structure of adsorbed substrate and mechanism of photoinduced reaction were discussed.
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title An in situ FT-IR Study on Photocatalytic Reaction at Semiconductor-Aqueous Solution Interface — Mechanism of Photocatalytic N-Cyclization of (S)-Lysine
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