Studies on Pyrazolo[3, 4-d]pyrimidne Derivatives. XVII. : Reactions of 5-Benzoyl-4, 5-dihydro-6-methyl-1-phenyl-1H-pyrazolo[3, 4-d]pyrimidine-4-carbonitrile

Acid hydrolysis of the 6-methylpyrazolopyrimidine Reissert compound (6) gave the ring-opened product (12) and the oxazole (13). Alkaline hydrolysis of 6 afforded the 6-methylpyrazolopyrimidine (7) and benzoic acid (15). The anion (1) of 6 mainly underwent both aromatization and rearrangement, result...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1990-01, Vol.38 (1), p.230
Hauptverfasser: MIYASHITA, Akira, SATO, Susumu, TAIDO, Naokata, TANJI, Ken-ichi, OISHI, Etsuo, HIGASHINO, Takeo
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Sprache:eng
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