A Method to Identify the Absolute Configuration of Rhamnose, Lyxose, and 2, 6-Dideoxy Sugars, Cymarose, Oleandrose, Diginose, and Digitoxose, Using a Chiral High-Performance Liquid Chromatography (HPLC) Column
D-Diginose and L-diginose (2, 6-dideoxy-3-O-methyl-lyxo-hexose) have been separated as the carbamoyl derivatives of the methyl glycosides by higy-performance liquid chromatography (HPLC) using a chiral column (SUMIPAX OA-4100).In the cases of other 2, 6-dideoxyhexoses, cymarose, oleandrose, and digi...
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Veröffentlicht in: | Chemical & pharmaceutical bulletin 1989/03/25, Vol.37(3), pp.637-641 |
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creator | TSUKAMOTO, Sachiko KANEKO, Koh HAYASHI, Koji |
description | D-Diginose and L-diginose (2, 6-dideoxy-3-O-methyl-lyxo-hexose) have been separated as the carbamoyl derivatives of the methyl glycosides by higy-performance liquid chromatography (HPLC) using a chiral column (SUMIPAX OA-4100).In the cases of other 2, 6-dideoxyhexoses, cymarose, oleandrose, and digitoxose, this column was more suitable for the enantiomeric separation than the column previously used (SUMIPAX OA-1000).The enantiomeric mixtures of cymarose obtained from Cynanchum wilfordi glycosides were analyzed by using the SUMIPAX OA-4100 column.Further, the enantiomers of rhamnose and lyxose have been separated as the carbamoyl derivatives of the acetonides by means of the chiral column. |
doi_str_mv | 10.1248/cpb.37.637 |
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Drug treatments ; rhamnose</subject><ispartof>Chemical and Pharmaceutical Bulletin, 1989/03/25, Vol.37(3), pp.637-641</ispartof><rights>The Pharmaceutical Society of Japan</rights><rights>1991 INIST-CNRS</rights><rights>Copyright Japan Science and Technology Agency 1989</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c511t-c8da9f461b9b933c8012173cb8c0d1fe772b6804109ea853a6819b35b27c11293</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1877,4010,27902,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19676043$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>TSUKAMOTO, Sachiko</creatorcontrib><creatorcontrib>KANEKO, Koh</creatorcontrib><creatorcontrib>HAYASHI, Koji</creatorcontrib><title>A Method to Identify the Absolute Configuration of Rhamnose, Lyxose, and 2, 6-Dideoxy Sugars, Cymarose, Oleandrose, Diginose, and Digitoxose, Using a Chiral High-Performance Liquid Chromatography (HPLC) Column</title><title>Chemical & pharmaceutical bulletin</title><addtitle>Chem. Pharm. Bull.</addtitle><description>D-Diginose and L-diginose (2, 6-dideoxy-3-O-methyl-lyxo-hexose) have been separated as the carbamoyl derivatives of the methyl glycosides by higy-performance liquid chromatography (HPLC) using a chiral column (SUMIPAX OA-4100).In the cases of other 2, 6-dideoxyhexoses, cymarose, oleandrose, and digitoxose, this column was more suitable for the enantiomeric separation than the column previously used (SUMIPAX OA-1000).The enantiomeric mixtures of cymarose obtained from Cynanchum wilfordi glycosides were analyzed by using the SUMIPAX OA-4100 column.Further, the enantiomers of rhamnose and lyxose have been separated as the carbamoyl derivatives of the acetonides by means of the chiral column.</description><subject>2, 6-dideoxy sugar</subject><subject>3, 5-dinitrophenylcarbamate</subject><subject>absolute configuration</subject><subject>Analysis</subject><subject>Biological and medical sciences</subject><subject>chiral HPLC column</subject><subject>cymarose</subject><subject>diginose</subject><subject>digitoxose</subject><subject>General pharmacology</subject><subject>lyxose</subject><subject>Medical sciences</subject><subject>oleandrose</subject><subject>Pharmacology. Drug treatments</subject><subject>rhamnose</subject><issn>0009-2363</issn><issn>1347-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNpFkd1u1DAQhSMEEkvhhiewhJAo2iz-SeL4cpUCWymoFdDryHHsxKvE3tqO1Dwmb4S3qdqbGVvzzRmPT5J8RHCHcFZ-E6d2R-iuIPRVskEko2mOMXmdbCCELMWkIG-Td94fIcQ5pGST_NuDXzIMtgPBgutOmqDVAsIgwb71dpyDBJU1Svez40FbA6wCvwc-GevlFtTLw2PmpgN4C4r0SnfSPizgz9xz57egWibuHpGbUUZqPV_pXpvnxvMt2FXozmvTAw6qQTs-goPuh_RWOmXdxI2QoNb3s-5i2dmJB9s7fhoW8OVwW1eX8aHjPJn3yRvFRy8_POWL5O7H97_VIa1vfl5X-zoVOUIhFWXHmcoK1LKWESJKiDCiRLSlgB1SklLcFiXMEGSSlznhRYlYS_IWU4EQZuQi-bTqnpy9n6UPzdHOzsSRDcoKiCiLMVJfV0rE1b2Tqjk5Hf9kaRBszpY10bKG0CZaFuHPT5LcCz4qF3fW_qWDFbSAGYlctXJHH3gvnwHughajPEsilpdnWbKGqP5SHbhrpCH_AX9Prk8</recordid><startdate>1989</startdate><enddate>1989</enddate><creator>TSUKAMOTO, Sachiko</creator><creator>KANEKO, Koh</creator><creator>HAYASHI, Koji</creator><general>The Pharmaceutical Society of Japan</general><general>Maruzen</general><general>Japan Science and Technology Agency</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TK</scope><scope>7TM</scope><scope>7U9</scope><scope>H94</scope></search><sort><creationdate>1989</creationdate><title>A Method to Identify the Absolute Configuration of Rhamnose, Lyxose, and 2, 6-Dideoxy Sugars, Cymarose, Oleandrose, Diginose, and Digitoxose, Using a Chiral High-Performance Liquid Chromatography (HPLC) Column</title><author>TSUKAMOTO, Sachiko ; KANEKO, Koh ; HAYASHI, Koji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c511t-c8da9f461b9b933c8012173cb8c0d1fe772b6804109ea853a6819b35b27c11293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>2, 6-dideoxy sugar</topic><topic>3, 5-dinitrophenylcarbamate</topic><topic>absolute configuration</topic><topic>Analysis</topic><topic>Biological and medical sciences</topic><topic>chiral HPLC column</topic><topic>cymarose</topic><topic>diginose</topic><topic>digitoxose</topic><topic>General pharmacology</topic><topic>lyxose</topic><topic>Medical sciences</topic><topic>oleandrose</topic><topic>Pharmacology. Drug treatments</topic><topic>rhamnose</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>TSUKAMOTO, Sachiko</creatorcontrib><creatorcontrib>KANEKO, Koh</creatorcontrib><creatorcontrib>HAYASHI, Koji</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>AIDS and Cancer Research Abstracts</collection><jtitle>Chemical & pharmaceutical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>TSUKAMOTO, Sachiko</au><au>KANEKO, Koh</au><au>HAYASHI, Koji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Method to Identify the Absolute Configuration of Rhamnose, Lyxose, and 2, 6-Dideoxy Sugars, Cymarose, Oleandrose, Diginose, and Digitoxose, Using a Chiral High-Performance Liquid Chromatography (HPLC) Column</atitle><jtitle>Chemical & pharmaceutical bulletin</jtitle><addtitle>Chem. Pharm. Bull.</addtitle><date>1989</date><risdate>1989</risdate><volume>37</volume><issue>3</issue><spage>637</spage><epage>641</epage><pages>637-641</pages><issn>0009-2363</issn><eissn>1347-5223</eissn><coden>CPBTAL</coden><abstract>D-Diginose and L-diginose (2, 6-dideoxy-3-O-methyl-lyxo-hexose) have been separated as the carbamoyl derivatives of the methyl glycosides by higy-performance liquid chromatography (HPLC) using a chiral column (SUMIPAX OA-4100).In the cases of other 2, 6-dideoxyhexoses, cymarose, oleandrose, and digitoxose, this column was more suitable for the enantiomeric separation than the column previously used (SUMIPAX OA-1000).The enantiomeric mixtures of cymarose obtained from Cynanchum wilfordi glycosides were analyzed by using the SUMIPAX OA-4100 column.Further, the enantiomers of rhamnose and lyxose have been separated as the carbamoyl derivatives of the acetonides by means of the chiral column.</abstract><cop>Tokyo</cop><pub>The Pharmaceutical Society of Japan</pub><doi>10.1248/cpb.37.637</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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subjects | 2, 6-dideoxy sugar 3, 5-dinitrophenylcarbamate absolute configuration Analysis Biological and medical sciences chiral HPLC column cymarose diginose digitoxose General pharmacology lyxose Medical sciences oleandrose Pharmacology. Drug treatments rhamnose |
title | A Method to Identify the Absolute Configuration of Rhamnose, Lyxose, and 2, 6-Dideoxy Sugars, Cymarose, Oleandrose, Diginose, and Digitoxose, Using a Chiral High-Performance Liquid Chromatography (HPLC) Column |
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