A Novel Electrochemical Method of Acetylation of Alcohols by Methyl Acetate
A new electrochemical method of acetylation, using methyl acetate at room temperature, was developed. The current efficiency in all the reactions with primary alcohols exceeded 100%, ranging from 126 to 166%, indicating that this method of acetylation is advantageous for the preparation of acetates...
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| Veröffentlicht in: | Chemical & pharmaceutical bulletin 1987/04/25, Vol.35(4), pp.1608-1609 |
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| Sprache: | eng |
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| container_end_page | 1609 |
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| container_issue | 4 |
| container_start_page | 1608 |
| container_title | Chemical & pharmaceutical bulletin |
| container_volume | 35 |
| creator | MASUMIZU, TATSUYA NOZAWA, KOOHEI KAWAI, KEN-ICHI NAKAJIMA, SHOICHI |
| description | A new electrochemical method of acetylation, using methyl acetate at room temperature, was developed. The current efficiency in all the reactions with primary alcohols exceeded 100%, ranging from 126 to 166%, indicating that this method of acetylation is advantageous for the preparation of acetates from the viewpoint of energy economy. |
| doi_str_mv | 10.1248/cpb.35.1608 |
| format | Article |
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Pharm. Bull.</addtitle><description>A new electrochemical method of acetylation, using methyl acetate at room temperature, was developed. The current efficiency in all the reactions with primary alcohols exceeded 100%, ranging from 126 to 166%, indicating that this method of acetylation is advantageous for the preparation of acetates from the viewpoint of energy economy.</description><subject>acetic acid methyl ester</subject><subject>acetylation</subject><subject>alcoholate anion</subject><subject>alcoholysis</subject><subject>Chemistry</subject><subject>electrochemical reduction</subject><subject>Exact sciences and technology</subject><subject>Noncondensed benzenic compounds</subject><subject>Organic chemistry</subject><subject>Preparations and properties</subject><subject>transesterification</subject><issn>0009-2363</issn><issn>1347-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNpFkMtOwzAQRS0EEqWw4gciwQ6l-J1kWZXyEAU2sLYcxyap3LjYLlL-nqSpysYja86c0VwArhGcIUzze7UtZ4TNEIf5CZggQrOUYUxOwQRCWKSYcHIOLkJYQ4gZzMgEvM6Td_erbbK0WkXvVK03jZI2edOxdlXiTDJXOnZWxsa1-69VrnY2JGW3hzq7J2TUl-DMSBv01aFOwdfj8nPxnK4-nl4W81WqWE5jmjNYVTJjhLDC8DLDJpfMMF0aVJaM5VxzVBVYZgVlBkGZF5RQQnB_oIKqxGQKbkbv1rufnQ5RrN3Ot_1KgSiHiGLEaE_djZTyLgSvjdj6ZiN9JxAUQ1qiT0sQJoa0evr24JShP9942aomHEcyShEveI89jNg6RPmtj33pY6OsHpSoYPmgpeMz2P_btfRCt-QPvMmACA</recordid><startdate>1987</startdate><enddate>1987</enddate><creator>MASUMIZU, TATSUYA</creator><creator>NOZAWA, KOOHEI</creator><creator>KAWAI, KEN-ICHI</creator><creator>NAKAJIMA, SHOICHI</creator><general>The Pharmaceutical Society of Japan</general><general>Maruzen</general><general>Japan Science and Technology Agency</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TK</scope><scope>7TM</scope><scope>7U9</scope><scope>H94</scope></search><sort><creationdate>1987</creationdate><title>A Novel Electrochemical Method of Acetylation of Alcohols by Methyl Acetate</title><author>MASUMIZU, TATSUYA ; NOZAWA, KOOHEI ; KAWAI, KEN-ICHI ; NAKAJIMA, SHOICHI</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c584t-850dda753359f6b72f8a5f5ebf1bb5586e61d92a7945f10a89434332248c0cb23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>acetic acid methyl ester</topic><topic>acetylation</topic><topic>alcoholate anion</topic><topic>alcoholysis</topic><topic>Chemistry</topic><topic>electrochemical reduction</topic><topic>Exact sciences and technology</topic><topic>Noncondensed benzenic compounds</topic><topic>Organic chemistry</topic><topic>Preparations and properties</topic><topic>transesterification</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>MASUMIZU, TATSUYA</creatorcontrib><creatorcontrib>NOZAWA, KOOHEI</creatorcontrib><creatorcontrib>KAWAI, KEN-ICHI</creatorcontrib><creatorcontrib>NAKAJIMA, SHOICHI</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>AIDS and Cancer Research Abstracts</collection><jtitle>Chemical & pharmaceutical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>MASUMIZU, TATSUYA</au><au>NOZAWA, KOOHEI</au><au>KAWAI, KEN-ICHI</au><au>NAKAJIMA, SHOICHI</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Novel Electrochemical Method of Acetylation of Alcohols by Methyl Acetate</atitle><jtitle>Chemical & pharmaceutical bulletin</jtitle><addtitle>Chem. Pharm. Bull.</addtitle><date>1987</date><risdate>1987</risdate><volume>35</volume><issue>4</issue><spage>1608</spage><epage>1609</epage><pages>1608-1609</pages><issn>0009-2363</issn><eissn>1347-5223</eissn><coden>CPBTAL</coden><abstract>A new electrochemical method of acetylation, using methyl acetate at room temperature, was developed. The current efficiency in all the reactions with primary alcohols exceeded 100%, ranging from 126 to 166%, indicating that this method of acetylation is advantageous for the preparation of acetates from the viewpoint of energy economy.</abstract><cop>Tokyo</cop><pub>The Pharmaceutical Society of Japan</pub><doi>10.1248/cpb.35.1608</doi><tpages>2</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Chemical and Pharmaceutical Bulletin, 1987/04/25, Vol.35(4), pp.1608-1609 |
| issn | 0009-2363 1347-5223 |
| language | eng |
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| source | J-STAGE Free; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry |
| subjects | acetic acid methyl ester acetylation alcoholate anion alcoholysis Chemistry electrochemical reduction Exact sciences and technology Noncondensed benzenic compounds Organic chemistry Preparations and properties transesterification |
| title | A Novel Electrochemical Method of Acetylation of Alcohols by Methyl Acetate |
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