Anodic Phosphonylation of Anthracene

Anodic Phosphonylation of Anthracene

Controlled potential electrolysis of anthracene at a glassy carbon anode in acetonitrile containing an excess of triethylphosphite and subsequent treatment of the product with sodium iodide resulted in the formation of 9, 10-bis (diethylphosphonyl)-9, 10-dihydroanthracene. Anodic phosphonylation was...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1979/05/25, Vol.27(5), pp.1271-1273
Hauptverfasser: OHMORI, HIDENOBU, NAKAI, SHIRO, MASUI, MASAICHIRO
Format: Artikel
Sprache:eng
Schlagworte:
4'-methoxybenzanilide
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Zusammenfassung:Controlled potential electrolysis of anthracene at a glassy carbon anode in acetonitrile containing an excess of triethylphosphite and subsequent treatment of the product with sodium iodide resulted in the formation of 9, 10-bis (diethylphosphonyl)-9, 10-dihydroanthracene. Anodic phosphonylation was also performed on 4'-methoxybenzanilide to give 2'-diethylphosphonyl-4'-methoxybenzanilide.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.27.1271