Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc

Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc

Fluorescence characteristics of 8-quinolyl derivatives substituted with anionic dissociative group at the hydroxyl in 8-hydroxyquinoline were examined in relation to that of 8-methoxyquinoline. A remarkable effect of Cd (II) and Zn (II) on the increase in fluorescence intensity of both 8-quinolyl di...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical & pharmaceutical bulletin 1974/02/25, Vol.22(2), pp.375-384
Hauptverfasser: NAGASAWA, KINZO, ISHIDAKA, OSAMU
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 384
container_issue 2
container_start_page 375
container_title Chemical & pharmaceutical bulletin
container_volume 22
creator NAGASAWA, KINZO
ISHIDAKA, OSAMU
description Fluorescence characteristics of 8-quinolyl derivatives substituted with anionic dissociative group at the hydroxyl in 8-hydroxyquinoline were examined in relation to that of 8-methoxyquinoline. A remarkable effect of Cd (II) and Zn (II) on the increase in fluorescence intensity of both 8-quinolyl dihydrogen phosphate (8-QP) and 8-hydroxyquinoline carboxymethylate (8-HQCM) was observed. Fluorometric examinations of these compounds in the presence of Cd (II) or Zn (II) suggested a possible formation of the fluorescent chelate ; 8-QP-Cd (II) (1 : 1) and 8-HQCM-Zn (II) (1 : 1). Fluorometric determination of Cd (II) and Zn (II) was successfully achieved by measuring the increase in fluorescence intensity of 8-QP or 8-HQCM in the presence of these ions.
doi_str_mv 10.1248/cpb.22.375
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1459781574</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3131741961</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4375-37f6c76c59f9c0ab50484c3b05cce7eac384b87000ed2c2d5ff3dff8e78cbada3</originalsourceid><addsrcrecordid>eNpFkcFu1DAQhiNEJZbChSewxA3hxbHjtXOsQksrFbVSy4WL5Uxs1qvETu2kIi_FM-LdVHCxrZnvnxnPXxQfSrItaSW_wNhuKd0ywV8Vm5JVAnNK2etiQwipMWU79qZ4m9KBEMqJYJviz1U_h2gSGA8GNXsdNUwmujQ5SChYJPEdvt-HNO5DXPrPCD_MvZ1PT-07hBsd2_B7Gcy0X3r0NUuf9eSezYv4euliTj_NzofeeXMS3UwJXYxj7yCjwaMpoO8OYsCdyb0H59dwLtDobnDzcFL9dB7eFWdW98m8f7nPix9Xl4_NNb69-3bTXNxiqPLfMRN2B2IHvLY1EN1yUskKWEs4gBFGA5NVK0Veiuko0I5byzprpRESWt1pdl58XOuOMTzNJk3qEOboc0tVVrwWsuSiytSnlcqzpxSNVWN0g46LKok6-qGyH4pSlWfKcLPChzTpX-YfqmNedW-OaFlzecTpemTV_2x2RhnP_gLz15m2</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1459781574</pqid></control><display><type>article</type><title>Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>J-STAGE (Japan Science &amp; Technology Information Aggregator, Electronic) Freely Available Titles - Japanese</source><source>Free Full-Text Journals in Chemistry</source><creator>NAGASAWA, KINZO ; ISHIDAKA, OSAMU</creator><creatorcontrib>NAGASAWA, KINZO ; ISHIDAKA, OSAMU</creatorcontrib><description>Fluorescence characteristics of 8-quinolyl derivatives substituted with anionic dissociative group at the hydroxyl in 8-hydroxyquinoline were examined in relation to that of 8-methoxyquinoline. A remarkable effect of Cd (II) and Zn (II) on the increase in fluorescence intensity of both 8-quinolyl dihydrogen phosphate (8-QP) and 8-hydroxyquinoline carboxymethylate (8-HQCM) was observed. Fluorometric examinations of these compounds in the presence of Cd (II) or Zn (II) suggested a possible formation of the fluorescent chelate ; 8-QP-Cd (II) (1 : 1) and 8-HQCM-Zn (II) (1 : 1). Fluorometric determination of Cd (II) and Zn (II) was successfully achieved by measuring the increase in fluorescence intensity of 8-QP or 8-HQCM in the presence of these ions.</description><identifier>ISSN: 0009-2363</identifier><identifier>EISSN: 1347-5223</identifier><identifier>DOI: 10.1248/cpb.22.375</identifier><language>eng</language><publisher>Tokyo: The Pharmaceutical Society of Japan</publisher><ispartof>Chemical and Pharmaceutical Bulletin, 1974/02/25, Vol.22(2), pp.375-384</ispartof><rights>The Pharmaceutical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 1974</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4375-37f6c76c59f9c0ab50484c3b05cce7eac384b87000ed2c2d5ff3dff8e78cbada3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1876,4009,27902,27903,27904</link.rule.ids></links><search><creatorcontrib>NAGASAWA, KINZO</creatorcontrib><creatorcontrib>ISHIDAKA, OSAMU</creatorcontrib><title>Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc</title><title>Chemical &amp; pharmaceutical bulletin</title><addtitle>Chem. Pharm. Bull.</addtitle><description>Fluorescence characteristics of 8-quinolyl derivatives substituted with anionic dissociative group at the hydroxyl in 8-hydroxyquinoline were examined in relation to that of 8-methoxyquinoline. A remarkable effect of Cd (II) and Zn (II) on the increase in fluorescence intensity of both 8-quinolyl dihydrogen phosphate (8-QP) and 8-hydroxyquinoline carboxymethylate (8-HQCM) was observed. Fluorometric examinations of these compounds in the presence of Cd (II) or Zn (II) suggested a possible formation of the fluorescent chelate ; 8-QP-Cd (II) (1 : 1) and 8-HQCM-Zn (II) (1 : 1). Fluorometric determination of Cd (II) and Zn (II) was successfully achieved by measuring the increase in fluorescence intensity of 8-QP or 8-HQCM in the presence of these ions.</description><issn>0009-2363</issn><issn>1347-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1974</creationdate><recordtype>article</recordtype><recordid>eNpFkcFu1DAQhiNEJZbChSewxA3hxbHjtXOsQksrFbVSy4WL5Uxs1qvETu2kIi_FM-LdVHCxrZnvnxnPXxQfSrItaSW_wNhuKd0ywV8Vm5JVAnNK2etiQwipMWU79qZ4m9KBEMqJYJviz1U_h2gSGA8GNXsdNUwmujQ5SChYJPEdvt-HNO5DXPrPCD_MvZ1PT-07hBsd2_B7Gcy0X3r0NUuf9eSezYv4euliTj_NzofeeXMS3UwJXYxj7yCjwaMpoO8OYsCdyb0H59dwLtDobnDzcFL9dB7eFWdW98m8f7nPix9Xl4_NNb69-3bTXNxiqPLfMRN2B2IHvLY1EN1yUskKWEs4gBFGA5NVK0Veiuko0I5byzprpRESWt1pdl58XOuOMTzNJk3qEOboc0tVVrwWsuSiytSnlcqzpxSNVWN0g46LKok6-qGyH4pSlWfKcLPChzTpX-YfqmNedW-OaFlzecTpemTV_2x2RhnP_gLz15m2</recordid><startdate>1974</startdate><enddate>1974</enddate><creator>NAGASAWA, KINZO</creator><creator>ISHIDAKA, OSAMU</creator><general>The Pharmaceutical Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TK</scope><scope>7TM</scope><scope>7U9</scope><scope>H94</scope></search><sort><creationdate>1974</creationdate><title>Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc</title><author>NAGASAWA, KINZO ; ISHIDAKA, OSAMU</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4375-37f6c76c59f9c0ab50484c3b05cce7eac384b87000ed2c2d5ff3dff8e78cbada3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1974</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>NAGASAWA, KINZO</creatorcontrib><creatorcontrib>ISHIDAKA, OSAMU</creatorcontrib><collection>CrossRef</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>AIDS and Cancer Research Abstracts</collection><jtitle>Chemical &amp; pharmaceutical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>NAGASAWA, KINZO</au><au>ISHIDAKA, OSAMU</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc</atitle><jtitle>Chemical &amp; pharmaceutical bulletin</jtitle><addtitle>Chem. Pharm. Bull.</addtitle><date>1974</date><risdate>1974</risdate><volume>22</volume><issue>2</issue><spage>375</spage><epage>384</epage><pages>375-384</pages><issn>0009-2363</issn><eissn>1347-5223</eissn><abstract>Fluorescence characteristics of 8-quinolyl derivatives substituted with anionic dissociative group at the hydroxyl in 8-hydroxyquinoline were examined in relation to that of 8-methoxyquinoline. A remarkable effect of Cd (II) and Zn (II) on the increase in fluorescence intensity of both 8-quinolyl dihydrogen phosphate (8-QP) and 8-hydroxyquinoline carboxymethylate (8-HQCM) was observed. Fluorometric examinations of these compounds in the presence of Cd (II) or Zn (II) suggested a possible formation of the fluorescent chelate ; 8-QP-Cd (II) (1 : 1) and 8-HQCM-Zn (II) (1 : 1). Fluorometric determination of Cd (II) and Zn (II) was successfully achieved by measuring the increase in fluorescence intensity of 8-QP or 8-HQCM in the presence of these ions.</abstract><cop>Tokyo</cop><pub>The Pharmaceutical Society of Japan</pub><doi>10.1248/cpb.22.375</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0009-2363
ispartof Chemical and Pharmaceutical Bulletin, 1974/02/25, Vol.22(2), pp.375-384
issn 0009-2363
1347-5223
language eng
recordid cdi_proquest_journals_1459781574
source Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese; Free Full-Text Journals in Chemistry
title Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T13%3A19%3A15IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fluorescence%20Characteristics%20of%208-O-Phosphoryl,%20-Sulfuryl,%20and%20-Carboxymethyl%20Derivatives%20of%208-Hydroxyquinoline%20and%20Its%20Application%20to%20Micro-determination%20of%20Cadmium%20and%20Zinc&rft.jtitle=Chemical%20&%20pharmaceutical%20bulletin&rft.au=NAGASAWA,%20KINZO&rft.date=1974&rft.volume=22&rft.issue=2&rft.spage=375&rft.epage=384&rft.pages=375-384&rft.issn=0009-2363&rft.eissn=1347-5223&rft_id=info:doi/10.1248/cpb.22.375&rft_dat=%3Cproquest_cross%3E3131741961%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1459781574&rft_id=info:pmid/&rfr_iscdi=true