Molecular Recognition of Chiral Diporphyrin Receptor with a Macrocyclic Cavity for Intercalation of Aromatic Compounds

Chiral diporphyrin receptor 1, which has a macrocyclic cavity for the intercalation of aromatic guest molecules, was designed and synthesized from pyrrole in five steps. The binding constants (Ka) revealed the greater affinity of 1 for more electron-deficient aromatic guests. The complexation betwee...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2012-01, Vol.85 (1), p.101-109
Hauptverfasser:	Ema, Tadashi, Ura, Norichika, Eguchi, Katsuya, Sakai, Takashi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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