A Kinetic Study on Nucleophilic Displacement Reactions of Phenyl Y-Substituted-Phenyl Carbonates with Alkali Metal Ethoxides

Pseudo-first-order rate constants (kobsd) have been measured for reactions of phenyl Y-substituted-phenyl carbonates with alkali metal ethoxides (EtOM, M = Li, Na, and K). The plot of kobsd vs. [EtOM] curves upward for the reaction of diphenyl carbonate with EtOM but is linear for that with EtOK in...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2012-09, Vol.85 (9), p.1007
Hauptverfasser:	Um, Ik-Hwan, Seo, Ji-Yoon, Kang, Ji-Sun, An, Jun-Sung
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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