Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives
The first stable anthryldiphosphenes, 1 and 2, were synthesized by utilizing kinetic stabilization of 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) and 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl (Bbt) groups, and were characterized by spectroscopic and X-ray crystall...
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2010-05, Vol.83 (5), p.456-478 |
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| container_title | Bulletin of the Chemical Society of Japan |
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| creator | Tsurusaki, Akihiro Nagahora, Noriyoshi Sasamori, Takahiro Matsuda, Kazunari Kanemitsu, Yoshihiko Watanabe, Yasuaki Hosoi, Yoshinobu Furukawa, Yukio Tokitoh, Norihiro |
| description | The first stable anthryldiphosphenes, 1 and 2, were synthesized by utilizing kinetic stabilization of 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) and 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl (Bbt) groups, and were characterized by spectroscopic and X-ray crystallographic analyses. The UV–visible spectroscopic data suggested the electronic communication between the anthryl moiety and the P=P unit. It was found that TbtP=P(9-Anth) (1a: 9-Anth = 9-anthryl) showed weak fluorescence in hexane solution. Furthermore, the reactivities of anthryldiphosphene 1 with a chromium complex, chalcogenation reagents, a diene, and electron-deficient olefins have been revealed. |
| doi_str_mv | 10.1246/bcsj.20090295 |
| format | Article |
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The UV–visible spectroscopic data suggested the electronic communication between the anthryl moiety and the P=P unit. It was found that TbtP=P(9-Anth) (1a: 9-Anth = 9-anthryl) showed weak fluorescence in hexane solution. 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The UV–visible spectroscopic data suggested the electronic communication between the anthryl moiety and the P=P unit. It was found that TbtP=P(9-Anth) (1a: 9-Anth = 9-anthryl) showed weak fluorescence in hexane solution. Furthermore, the reactivities of anthryldiphosphene 1 with a chromium complex, chalcogenation reagents, a diene, and electron-deficient olefins have been revealed.</description><issn>0009-2673</issn><issn>1348-0634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNptkEtLw0AUhQdRsFaX7gNuTZ1XJhl3pT6xIFjdGiaTGzIlTeLMpBB_vVNawYWr--A793APQpcEzwjl4qbQbj2jGEtMZXKEJoTxLMaC8WM0wWEdU5GyU3Tm3DqMWcLlBH2uxtbX4Iy7jlbeDtoPFkKv2jJ6A6W92Ro_Rl0VvZgWvNGqacZAqsI05hvKaB7kdmxK09ed62toIboDa7YqKMGdo5NKNQ4uDnWKPh7u3xdP8fL18XkxX8aai8THpRKaZEqWHGSaccwVS0mScaBVITQDUmQMA2dKCqK5FEAlJZzTMilLhQVhU3S1v9vb7msA5_N1N9g2WOaEJ5LLJOUyUPGe0rZzzkKV99ZslB1zgvNdhPkuwvw3wsDfHvgaNrvXXacN-HGtetX-cfhX_AMA7XmU</recordid><startdate>20100515</startdate><enddate>20100515</enddate><creator>Tsurusaki, Akihiro</creator><creator>Nagahora, Noriyoshi</creator><creator>Sasamori, Takahiro</creator><creator>Matsuda, Kazunari</creator><creator>Kanemitsu, Yoshihiko</creator><creator>Watanabe, Yasuaki</creator><creator>Hosoi, Yoshinobu</creator><creator>Furukawa, Yukio</creator><creator>Tokitoh, Norihiro</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20100515</creationdate><title>Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives</title><author>Tsurusaki, Akihiro ; Nagahora, Noriyoshi ; Sasamori, Takahiro ; Matsuda, Kazunari ; Kanemitsu, Yoshihiko ; Watanabe, Yasuaki ; Hosoi, Yoshinobu ; Furukawa, Yukio ; Tokitoh, Norihiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c465t-da6c18a9d4e978404a371584e2fb6c3e1b830e43a961c496e2921442d5dda0613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tsurusaki, Akihiro</creatorcontrib><creatorcontrib>Nagahora, Noriyoshi</creatorcontrib><creatorcontrib>Sasamori, Takahiro</creatorcontrib><creatorcontrib>Matsuda, Kazunari</creatorcontrib><creatorcontrib>Kanemitsu, Yoshihiko</creatorcontrib><creatorcontrib>Watanabe, Yasuaki</creatorcontrib><creatorcontrib>Hosoi, Yoshinobu</creatorcontrib><creatorcontrib>Furukawa, Yukio</creatorcontrib><creatorcontrib>Tokitoh, Norihiro</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Bulletin of the Chemical Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tsurusaki, Akihiro</au><au>Nagahora, Noriyoshi</au><au>Sasamori, Takahiro</au><au>Matsuda, Kazunari</au><au>Kanemitsu, Yoshihiko</au><au>Watanabe, Yasuaki</au><au>Hosoi, Yoshinobu</au><au>Furukawa, Yukio</au><au>Tokitoh, Norihiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives</atitle><jtitle>Bulletin of the Chemical Society of Japan</jtitle><addtitle>Bulletin of the Chemical Society of Japan</addtitle><date>2010-05-15</date><risdate>2010</risdate><volume>83</volume><issue>5</issue><spage>456</spage><epage>478</epage><pages>456-478</pages><issn>0009-2673</issn><eissn>1348-0634</eissn><abstract>The first stable anthryldiphosphenes, 1 and 2, were synthesized by utilizing kinetic stabilization of 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) and 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl (Bbt) groups, and were characterized by spectroscopic and X-ray crystallographic analyses. The UV–visible spectroscopic data suggested the electronic communication between the anthryl moiety and the P=P unit. It was found that TbtP=P(9-Anth) (1a: 9-Anth = 9-anthryl) showed weak fluorescence in hexane solution. Furthermore, the reactivities of anthryldiphosphene 1 with a chromium complex, chalcogenation reagents, a diene, and electron-deficient olefins have been revealed.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/bcsj.20090295</doi><tpages>23</tpages><oa>free_for_read</oa></addata></record> |
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| source | Oxford University Press Journals All Titles (1996-Current) |
| title | Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives |
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