Effect of Hydration on the Very Slow Droplet-Lamellar Transition in Dioleylsulfosuccinate/Decane/Water System

Time- and temperature-dependence of the small angle X-ray scattering (SAXS) profiles for homogeneous and transparent solutions of the sodium dioleylsulfosuccinate (SDOleS)-decane-water system with various molar ratios of [H2O]/[SDOleS] have been examined. The time-dependence of the SAXS profiles has...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2009-06, Vol.82 (6), p.664
Hauptverfasser: K. Ghosh, Swapan, Ichiyanagi, Naoki, Okabayashi, Hiro-Fumi, Yoshino, Aki-Hiro, Takeda, Takayoshi, J. O'Connor, Charmian
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container_issue 6
container_start_page 664
container_title Bulletin of the Chemical Society of Japan
container_volume 82
creator K. Ghosh, Swapan
Ichiyanagi, Naoki
Okabayashi, Hiro-Fumi
Yoshino, Aki-Hiro
Takeda, Takayoshi
J. O'Connor, Charmian
description Time- and temperature-dependence of the small angle X-ray scattering (SAXS) profiles for homogeneous and transparent solutions of the sodium dioleylsulfosuccinate (SDOleS)-decane-water system with various molar ratios of [H2O]/[SDOleS] have been examined. The time-dependence of the SAXS profiles has provided evidence that the droplet-lamellar transition occurs spontaneously but very slowly at 298 K. This behavior depends upon the quantity of water solubilized into the SDOleS microemulsions. Some microstructural models have been proposed to explain this very slow transition.
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source Oxford University Press Journals All Titles (1996-Current)
title Effect of Hydration on the Very Slow Droplet-Lamellar Transition in Dioleylsulfosuccinate/Decane/Water System
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