Hyperconjugative Electron-Delocalization Mechanism Controlling the Conformational Preference of Fluoroacetaldehyde and Methyl Fluoroacetate

We confirmed by both canonical molecular orbital analysis and the orbital deletion procedure (ODP) that a hyperconjugative electron-delocalization mechanism is the main factor controlling the conformational preference for cis and trans conformations of fluoroacetaldehyde (FAA) and methyl fluoroaceta...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2006, Vol.79 (4), p.555-560
Hauptverfasser:	Sahnoun, Riadh, Fujimura, Yuichi, Kabuto, Kuninobu, Takeuchi, Yoshio, Noyori, Ryoji
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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