Fabrication of Solid-State Dye-Sensitized TiO2 Solar Cell Using Polymer Electrolyte

Fabrication of Solid-State Dye-Sensitized TiO2 Solar Cell Using Polymer Electrolyte

A solid-state dye-sensitized TiO2 solar cell has been fabricated with a polymer electrolyte constructed with α-methacryloyl-ω-methoxyocta(oxyethylene) or 2-(2-methoxyethoxy)ethyl acrylate as a base polymer, α-acryloyl-ω-acryloyloxyocta(oxyethylene)octa(ethylene glycol) dimethacrylate as a cross-link...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2001-02, Vol.74 (2), p.387-393
Hauptverfasser: Matsumoto, Masamitsu, Wada, Yuji, Kitamura, Takayuki, Shigaki, Kouichiro, Inoue, Teruhisa, Ikeda, Masaaki, Yanagida, Shozo
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container_end_page 393
container_issue 2
container_start_page 387
container_title Bulletin of the Chemical Society of Japan
container_volume 74
creator Matsumoto, Masamitsu
Wada, Yuji
Kitamura, Takayuki
Shigaki, Kouichiro
Inoue, Teruhisa
Ikeda, Masaaki
Yanagida, Shozo
description A solid-state dye-sensitized TiO2 solar cell has been fabricated with a polymer electrolyte constructed with α-methacryloyl-ω-methoxyocta(oxyethylene) or 2-(2-methoxyethoxy)ethyl acrylate as a base polymer, α-acryloyl-ω-acryloyloxyocta(oxyethylene)octa(ethylene glycol) dimethacrylate as a cross-linking agent and 3-methoxypropiononitrile as a plasticizer. The polymer is in-situ polymerized at the porous TiO2 film by photo-irradiation and the resulting film is immersed into the liquid electrolyte in order to introduce the electrolyte to the polymer phase. The conductivity of the polymer electrolyte reached 2.67 mS cm-1. The energy conversion efficiency of the solid-state cell was 2.62% under irradiation of simulated sunlight (AM 1.5, 1 kW m-2), achieving 86.4% of the cell efficiency using the liquid electrolyte.
doi_str_mv 10.1246/bcsj.74.387
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source Oxford University Press Journals All Titles (1996-Current)
title Fabrication of Solid-State Dye-Sensitized TiO2 Solar Cell Using Polymer Electrolyte
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