Behaviors of the One-Electron Reduction Species of {RuNO}6-Type Complexes. An Oxygen-Transfer Reaction Occurs in the Nitrosyl Site of cis-[Ru(NO·)X(bpy)2]n+ (X = ONO2 for n = 1, X = CH3CN, H2O for n = 2) ({RuNO}7-Type) to Give an Identical Nitro Species

Degradation sequences of cis-[Ru(NO·)X(bpy)2]n+ (X = ONO2, OCHO, OCOMe, NO2, Cl for n = 1; X = CH3CN, H2O for n = 2) ({RuNO}7-type), a one-electron reduction species of {RuNO}6-type complexes, were investigated in CH3CN by monitoring using electrochemical techniques (both cyclic and hydrodynamic vol...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2000-01, Vol.73 (1), p.85-95
Hauptverfasser:	Mukaida, Masao, Sato, Yoshinobu, Kato, Hideji, Mori, Mami, Ooyama, Dai, Nagao, Hirotaka, Howell, F. Scott
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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