A Better Synthesis of Biruthenocene and Molecular Structures of [RuIICp(C5H4C5H4)CpRuIVNCC2H5](BF4)(B2F7)CH3NO2, [RuIICp(2,2′-bipyridine)(p-benzoquinone)]BF4 and Related Salts

An interesting dimerization occurred during the oxidation of ruthenocene with an excess of p-benzoquinone containing BF3·Et2O (abbreviated p-Bq/BF3) in a mixed solution of benzene and hexane, which gave biruthenocenium(BF4)2 (A) in 89% yield. Reduction of A with TiCl3 gave biruthenocene in a good yi...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 1999-04, Vol.72 (4), p.715-723
Hauptverfasser:	Watanabe, Masanobu, Sato, Masaru, Nagasawa, Akira, Kai, Masahiro, Motoyama, Izumi, Takayama, Toshio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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