Absolute configuration of a ceramide with a novel branched-chain fatty acid isolated from the epiphytic dinoflagellate, Coolia monotis

The absolute configuration of the chiral center at the C15 position of a novel branched-chain fatty acid derived from a new ceramide isolated from the epiphytic dinoflagellate Coolia monotis was determined to be of R from by reversed-phase HPLC after cleavage to 12-methylpentadecanoic acid and subse...

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Veröffentlicht in:Bioscience, biotechnology, and biochemistry biotechnology, and biochemistry, 2000-09, Vol.64 (9), p.1842-1846
Hauptverfasser: Akasaka, K. (Tohoku Univ., Sendai (Japan)), Shichijyukari, S, Matsuoka, S, Murata, M, Meguro, H, Ohrui, H
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container_end_page 1846
container_issue 9
container_start_page 1842
container_title Bioscience, biotechnology, and biochemistry
container_volume 64
creator Akasaka, K. (Tohoku Univ., Sendai (Japan))
Shichijyukari, S
Matsuoka, S
Murata, M
Meguro, H
Ohrui, H
description The absolute configuration of the chiral center at the C15 position of a novel branched-chain fatty acid derived from a new ceramide isolated from the epiphytic dinoflagellate Coolia monotis was determined to be of R from by reversed-phase HPLC after cleavage to 12-methylpentadecanoic acid and subsequent conversion with the chiral fluorescent reagent, (1R,2R)-2-(2,3-anthracenedicarboximido)cyclohexanol.
doi_str_mv 10.1271/bbb.64.1842
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source Oxford University Press Journals All Titles (1996-Current); MEDLINE; J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese; Open Access Titles of Japan; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry
subjects absolute configuration
ANALYTICAL METHODS
Animals
Biological and medical sciences
branched-chain fatty acid
Ceramides - chemistry
Ceramides - isolation & purification
Chemical constitution
CHEMICAL STRUCTURE
chiral conversion reagent
chiral discrimination
Chromatography, High Pressure Liquid
Dinoflagellida - chemistry
EPIPHYTES
FATTY ACIDS
Fluorescent Dyes
Fundamental and applied biological sciences. Psychology
HPLC
Indicators and Reagents
LIPIDS
MASTIGOPHORA
Molecular Structure
Plant physiology and development
Stereoisomerism
title Absolute configuration of a ceramide with a novel branched-chain fatty acid isolated from the epiphytic dinoflagellate, Coolia monotis
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