Photocathodic protection properties of TiO2-V2O5 composite coatings

TiO2/vanadium pentoxide (V2O5) and TiO2–V2O5 coatings were prepared on type 304 stainless steel substrates via a sol–gel method, respectively. The TiO2/V2O5 coating is compared with the TiO2–V2O5 coating in terms of the photo‐electrochemical performance. The two coatings can be stored with photogene...

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Veröffentlicht in:Materials and corrosion 2013-11, Vol.64 (11), p.996-1000
Hauptverfasser: Zhou, M.-J., Zhang, N., Zhang, L., Yan, J.-H.
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container_title Materials and corrosion
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creator Zhou, M.-J.
Zhang, N.
Zhang, L.
Yan, J.-H.
description TiO2/vanadium pentoxide (V2O5) and TiO2–V2O5 coatings were prepared on type 304 stainless steel substrates via a sol–gel method, respectively. The TiO2/V2O5 coating is compared with the TiO2–V2O5 coating in terms of the photo‐electrochemical performance. The two coatings can be stored with photogenerated electrons under UV irradiation in 3 wt% aqueous NaCl. The self‐discharging time of the TiO2/V2O5 coating is slower than that of the TiO2–V2O5 coating. The slow discharging may be suitable for an anti‐corrosion application for stainless steel. In the case while the two coatings are electrochemically charged under UV irradiation for 1 h, the TiO2/V2O5 coating can maintain a good cathodic protection for type 304 stainless steel for 6 h in the dark, while the TiO2–V2O5 coating can only maintain a good cathode protection for 0.5 h in the dark.
doi_str_mv 10.1002/maco.201106418
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The TiO2/V2O5 coating is compared with the TiO2–V2O5 coating in terms of the photo‐electrochemical performance. The two coatings can be stored with photogenerated electrons under UV irradiation in 3 wt% aqueous NaCl. The self‐discharging time of the TiO2/V2O5 coating is slower than that of the TiO2–V2O5 coating. The slow discharging may be suitable for an anti‐corrosion application for stainless steel. In the case while the two coatings are electrochemically charged under UV irradiation for 1 h, the TiO2/V2O5 coating can maintain a good cathodic protection for type 304 stainless steel for 6 h in the dark, while the TiO2–V2O5 coating can only maintain a good cathode protection for 0.5 h in the dark.</description><identifier>ISSN: 0947-5117</identifier><identifier>EISSN: 1521-4176</identifier><identifier>DOI: 10.1002/maco.201106418</identifier><identifier>CODEN: MTCREQ</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; Cathodic protection ; Corrosion ; Corrosion environments ; energy storage ; Exact sciences and technology ; Metals. Metallurgy ; photocathodic protection ; Production techniques ; Stainless steel ; Surface treatment ; TiO2-V2O5 coating</subject><ispartof>Materials and corrosion, 2013-11, Vol.64 (11), p.996-1000</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH &amp; Co. 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subjects Applied sciences
Cathodic protection
Corrosion
Corrosion environments
energy storage
Exact sciences and technology
Metals. Metallurgy
photocathodic protection
Production techniques
Stainless steel
Surface treatment
TiO2-V2O5 coating
title Photocathodic protection properties of TiO2-V2O5 composite coatings
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