Modification of Novel Conductive PEDOT:Sulfonated Polyimide Nano-Thin Films by Anionic Surfactant and Poly(vinyl alcohol) for Electronic Applications
Conductive poly(3,4-ethylenedioxythiophene):sulfonated polyimide (PEDOT: SPI) nanoscale thin films were successfully developed by addition of anionic surfactant and poly(vinyl alcohol) (PVA) for potential application in electronic devices. In this work, sodium dodecyl sulfate (SDS) surfactant was in...
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| Veröffentlicht in: | Journal of electronic materials 2013-12, Vol.42 (12), p.3471-3480 |
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| creator | Romyen, Nathavat Thongyai, Supakanok Praserthdam, Piyasan Sotzing, Gregory A. |
| description | Conductive poly(3,4-ethylenedioxythiophene):sulfonated polyimide (PEDOT: SPI) nanoscale thin films were successfully developed by addition of anionic surfactant and poly(vinyl alcohol) (PVA) for potential application in electronic devices. In this work, sodium dodecyl sulfate (SDS) surfactant was introduced into PEDOT:SPI aqueous suspensions to improve the dispersion stability of the particles in water, leading to high transparency and low contact angle of PEDOT:SPI thin films. All of the conducting polymer thin films showed high transparency of more than 85% transmission. Conductivity enhancement and good film-formation properties of PEDOT:SPI were achieved by adding various amounts of PVA to each polymer aqueous suspension because of the resulting conformational changes. The highest conductivity of 0.134 S/cm was achieved at 0.08 wt.% PVA in PEDOT:SPI2/SDS/PVA film, increased by a factor of 3.5 compared with the original material. In addition, PVA also improved the thermal stability of the conductive films, as verified by thermogravimetric analysis (TGA). The interactions between conducting polymers, PVA, and SDS surfactant affecting nano-thin film properties were revealed and investigated. Moreover, the interactions between SDS and SPI were proven to be different from those between SDS and poly(styrenesulfonate) (PSS) in conventional PEDOT:PSS solutions. |
| doi_str_mv | 10.1007/s11664-013-2816-4 |
| format | Article |
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In this work, sodium dodecyl sulfate (SDS) surfactant was introduced into PEDOT:SPI aqueous suspensions to improve the dispersion stability of the particles in water, leading to high transparency and low contact angle of PEDOT:SPI thin films. All of the conducting polymer thin films showed high transparency of more than 85% transmission. Conductivity enhancement and good film-formation properties of PEDOT:SPI were achieved by adding various amounts of PVA to each polymer aqueous suspension because of the resulting conformational changes. The highest conductivity of 0.134 S/cm was achieved at 0.08 wt.% PVA in PEDOT:SPI2/SDS/PVA film, increased by a factor of 3.5 compared with the original material. In addition, PVA also improved the thermal stability of the conductive films, as verified by thermogravimetric analysis (TGA). The interactions between conducting polymers, PVA, and SDS surfactant affecting nano-thin film properties were revealed and investigated. 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Moreover, the interactions between SDS and SPI were proven to be different from those between SDS and poly(styrenesulfonate) (PSS) in conventional PEDOT:PSS solutions.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Conductivity</subject><subject>Electronics and Microelectronics</subject><subject>Exact sciences and technology</subject><subject>Instrumentation</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Physics</subject><subject>Polymers</subject><subject>Polyvinyl alcohol</subject><subject>Solid State Physics</subject><subject>Thermal expansion; thermomechanical effects and density</subject><subject>Thermal properties of condensed matter</subject><subject>Thermal properties of crystalline solids</subject><subject>Thin films</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp1kM1uEzEURkcIJELhAdhZQkiwcPH1-G_YRSGFSqWt1CCxszyOTV05drBnIuVBeF-mTITYsLqL-33nXp2meQ3kHAiRHyqAEAwTaDFVIDB70iyAsxaDEt-fNgvSCsCctvx586LWB0KAg4JF8-tr3gYfrBlCTih7dJ0PLqJVTtvRDuHg0O36083m490YfU5mcFt0m-Mx7MLWoWuTMt7ch4QuQtxV1B_RMk2cYNHdWLyxg0kDMmnuvDuEdIzIRJvvc3yPfC5oHZ0dyp_Gcr-Ppz_qy-aZN7G6V6d51ny7WG9WX_DVzefL1fIK25aJAYPhrqcgrZRWCElNT5lSwgouO2CGKauIt11LPZdcEEuhJ7aXpoNWMNFCe9a8mbn7kn-Org76IY8lTSc1MKY6RUDwKQVzypZca3Fe70vYmXLUQPSjfT3b15N9_Whfs6nz9kQ21Zroi0k21L9FKjspFKVTjs65Oq3SD1f--eC_8N96ZZUF</recordid><startdate>20131201</startdate><enddate>20131201</enddate><creator>Romyen, Nathavat</creator><creator>Thongyai, Supakanok</creator><creator>Praserthdam, Piyasan</creator><creator>Sotzing, Gregory A.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope></search><sort><creationdate>20131201</creationdate><title>Modification of Novel Conductive PEDOT:Sulfonated Polyimide Nano-Thin Films by Anionic Surfactant and Poly(vinyl alcohol) for Electronic Applications</title><author>Romyen, Nathavat ; Thongyai, Supakanok ; Praserthdam, Piyasan ; Sotzing, Gregory A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-1a5eb217c77c6672ab24886c657914a48c80fc932f57560c21b0cb7a913646313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Conductivity</topic><topic>Electronics and Microelectronics</topic><topic>Exact sciences and technology</topic><topic>Instrumentation</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Physics</topic><topic>Polymers</topic><topic>Polyvinyl alcohol</topic><topic>Solid State Physics</topic><topic>Thermal expansion; thermomechanical effects and density</topic><topic>Thermal properties of condensed matter</topic><topic>Thermal properties of crystalline solids</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Romyen, Nathavat</creatorcontrib><creatorcontrib>Thongyai, Supakanok</creatorcontrib><creatorcontrib>Praserthdam, Piyasan</creatorcontrib><creatorcontrib>Sotzing, Gregory A.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Romyen, Nathavat</au><au>Thongyai, Supakanok</au><au>Praserthdam, Piyasan</au><au>Sotzing, Gregory A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modification of Novel Conductive PEDOT:Sulfonated Polyimide Nano-Thin Films by Anionic Surfactant and Poly(vinyl alcohol) for Electronic Applications</atitle><jtitle>Journal of electronic materials</jtitle><stitle>Journal of Elec Materi</stitle><date>2013-12-01</date><risdate>2013</risdate><volume>42</volume><issue>12</issue><spage>3471</spage><epage>3480</epage><pages>3471-3480</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><coden>JECMA5</coden><abstract>Conductive poly(3,4-ethylenedioxythiophene):sulfonated polyimide (PEDOT: SPI) nanoscale thin films were successfully developed by addition of anionic surfactant and poly(vinyl alcohol) (PVA) for potential application in electronic devices. In this work, sodium dodecyl sulfate (SDS) surfactant was introduced into PEDOT:SPI aqueous suspensions to improve the dispersion stability of the particles in water, leading to high transparency and low contact angle of PEDOT:SPI thin films. All of the conducting polymer thin films showed high transparency of more than 85% transmission. Conductivity enhancement and good film-formation properties of PEDOT:SPI were achieved by adding various amounts of PVA to each polymer aqueous suspension because of the resulting conformational changes. The highest conductivity of 0.134 S/cm was achieved at 0.08 wt.% PVA in PEDOT:SPI2/SDS/PVA film, increased by a factor of 3.5 compared with the original material. In addition, PVA also improved the thermal stability of the conductive films, as verified by thermogravimetric analysis (TGA). The interactions between conducting polymers, PVA, and SDS surfactant affecting nano-thin film properties were revealed and investigated. Moreover, the interactions between SDS and SPI were proven to be different from those between SDS and poly(styrenesulfonate) (PSS) in conventional PEDOT:PSS solutions.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s11664-013-2816-4</doi><tpages>10</tpages></addata></record> |
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| ispartof | Journal of electronic materials, 2013-12, Vol.42 (12), p.3471-3480 |
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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Condensed matter: structure, mechanical and thermal properties Conductivity Electronics and Microelectronics Exact sciences and technology Instrumentation Materials Science Optical and Electronic Materials Physics Polymers Polyvinyl alcohol Solid State Physics Thermal expansion thermomechanical effects and density Thermal properties of condensed matter Thermal properties of crystalline solids Thin films |
| title | Modification of Novel Conductive PEDOT:Sulfonated Polyimide Nano-Thin Films by Anionic Surfactant and Poly(vinyl alcohol) for Electronic Applications |
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