Determination of titanium, zirconium, lead and additives in lead zirconate titanate by ICP-AES
A powdered (agate pot and vibrating mixer mill is used) sample (0.2g) is decomposed with a mixed acid solution (15ml of hydrochloric acid +1ml of hydrofluoric acid) in a Teflon bomb. When the resultant solution is diluted directly with water, large quantities of precipitates (consisting of titanium,...
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| Veröffentlicht in: | BUNSEKI KAGAKU 1986/09/05, Vol.35(9), pp.T76-T79 |
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| container_issue | 9 |
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| container_title | BUNSEKI KAGAKU |
| container_volume | 35 |
| creator | HARA, Hideo HASHIMOTO, Toshio FUJIE, Shinichi GOHSHI, Yohichi |
| description | A powdered (agate pot and vibrating mixer mill is used) sample (0.2g) is decomposed with a mixed acid solution (15ml of hydrochloric acid +1ml of hydrofluoric acid) in a Teflon bomb. When the resultant solution is diluted directly with water, large quantities of precipitates (consisting of titanium, zirconium and lead compounds etc.) are observed. To avoid this, the following procedure is employed; The solution is transferred into a polyethylene beaker containing 1.5g of citric acid. After pH adjustment to 89, most of the precipitates can be dissolved by the addition of 2.0g of EDTA·2Na. The remaining LaF3 precipitate is dissolved by heating with 1.5g of boric acid and 20 ml of nitric acid. After cooling, this solution is used for rinsing the bomb, and is transferred into a 250ml volumetric flask. An aliquot of 25ml is diluted four times with water and analysed by ICP-AES. The procedure described here provides a rapid and precise (R.S.D. |
| doi_str_mv | 10.2116/bunsekikagaku.35.9_T76 |
| format | Article |
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When the resultant solution is diluted directly with water, large quantities of precipitates (consisting of titanium, zirconium and lead compounds etc.) are observed. To avoid this, the following procedure is employed; The solution is transferred into a polyethylene beaker containing 1.5g of citric acid. After pH adjustment to 89, most of the precipitates can be dissolved by the addition of 2.0g of EDTA·2Na. The remaining LaF3 precipitate is dissolved by heating with 1.5g of boric acid and 20 ml of nitric acid. After cooling, this solution is used for rinsing the bomb, and is transferred into a 250ml volumetric flask. An aliquot of 25ml is diluted four times with water and analysed by ICP-AES. The procedure described here provides a rapid and precise (R.S.D.<3%) determination for all elements (Ti, Zr, Pb, Nb, Sr, La, Cr, Mn and Mg) without erosion of glassware and quartzware (plasma torch, nebulizer etc.).</description><identifier>ISSN: 0525-1931</identifier><identifier>DOI: 10.2116/bunsekikagaku.35.9_T76</identifier><language>eng ; jpn</language><publisher>Tokyo: The Japan Society for Analytical Chemistry</publisher><subject>chromium ; determination of niobium ; ICP-AES ; lanthanum ; lead zirconate titanate analysis ; manganese and magnesium ; strontium</subject><ispartof>BUNSEKI KAGAKU, 1986/09/05, Vol.35(9), pp.T76-T79</ispartof><rights>The Japan Society for Analytical Chemistry</rights><rights>Copyright Japan Science and Technology Agency 1986</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1877,4010,27900,27901,27902</link.rule.ids></links><search><creatorcontrib>HARA, Hideo</creatorcontrib><creatorcontrib>HASHIMOTO, Toshio</creatorcontrib><creatorcontrib>FUJIE, Shinichi</creatorcontrib><creatorcontrib>GOHSHI, Yohichi</creatorcontrib><title>Determination of titanium, zirconium, lead and additives in lead zirconate titanate by ICP-AES</title><title>BUNSEKI KAGAKU</title><addtitle>BUNSEKI KAGAKU</addtitle><description>A powdered (agate pot and vibrating mixer mill is used) sample (0.2g) is decomposed with a mixed acid solution (15ml of hydrochloric acid +1ml of hydrofluoric acid) in a Teflon bomb. When the resultant solution is diluted directly with water, large quantities of precipitates (consisting of titanium, zirconium and lead compounds etc.) are observed. To avoid this, the following procedure is employed; The solution is transferred into a polyethylene beaker containing 1.5g of citric acid. After pH adjustment to 89, most of the precipitates can be dissolved by the addition of 2.0g of EDTA·2Na. The remaining LaF3 precipitate is dissolved by heating with 1.5g of boric acid and 20 ml of nitric acid. After cooling, this solution is used for rinsing the bomb, and is transferred into a 250ml volumetric flask. An aliquot of 25ml is diluted four times with water and analysed by ICP-AES. The procedure described here provides a rapid and precise (R.S.D.<3%) determination for all elements (Ti, Zr, Pb, Nb, Sr, La, Cr, Mn and Mg) without erosion of glassware and quartzware (plasma torch, nebulizer etc.).</description><subject>chromium</subject><subject>determination of niobium</subject><subject>ICP-AES</subject><subject>lanthanum</subject><subject>lead zirconate titanate analysis</subject><subject>manganese and magnesium</subject><subject>strontium</subject><issn>0525-1931</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNpVkMlOwzAQhnMAiar0FVAkrqR4iRP7WJWtUhFIlCvWOLGLuyRgO0jl6UkxVOphNKPR_83yJ8kFRmOCcXGtusbrtV3DEtbdmLKxkIuyOEkGiBGWYUHxWTLy3iqECCcEkXyQvN3ooN3WNhBs26StSYMN0Nhue5V-W1e1sdxoqFNo-qhrG-yX9qltYjeqIOhI7gu1S2fT52xy-3KenBrYeD36y8Pk9e52MX3I5k_3s-lknlWUoCJjpmDc8LLi2lQGMVFzXUOBQNVASoEFwpopleOSK8SV0BgJKGqaY8GAGkOHyWWc--Haz077IFdt55p-pcR5zrko--97VRFVlWu9d9rID2e34HYSI7m3UB5ZKCmTvxb24GMEVz7AUh8wcMFWG32M9TeRiP7zB131Dk7qhv4AywaH2Q</recordid><startdate>1986</startdate><enddate>1986</enddate><creator>HARA, Hideo</creator><creator>HASHIMOTO, Toshio</creator><creator>FUJIE, Shinichi</creator><creator>GOHSHI, Yohichi</creator><general>The Japan Society for Analytical Chemistry</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>1986</creationdate><title>Determination of titanium, zirconium, lead and additives in lead zirconate titanate by ICP-AES</title><author>HARA, Hideo ; HASHIMOTO, Toshio ; FUJIE, Shinichi ; GOHSHI, Yohichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3206-5f658f87c8efcf059d8eda60abda2791901e5bb4178b08b9e109a6d34195a3ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1986</creationdate><topic>chromium</topic><topic>determination of niobium</topic><topic>ICP-AES</topic><topic>lanthanum</topic><topic>lead zirconate titanate analysis</topic><topic>manganese and magnesium</topic><topic>strontium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HARA, Hideo</creatorcontrib><creatorcontrib>HASHIMOTO, Toshio</creatorcontrib><creatorcontrib>FUJIE, Shinichi</creatorcontrib><creatorcontrib>GOHSHI, Yohichi</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>BUNSEKI KAGAKU</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HARA, Hideo</au><au>HASHIMOTO, Toshio</au><au>FUJIE, Shinichi</au><au>GOHSHI, Yohichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of titanium, zirconium, lead and additives in lead zirconate titanate by ICP-AES</atitle><jtitle>BUNSEKI KAGAKU</jtitle><addtitle>BUNSEKI KAGAKU</addtitle><date>1986</date><risdate>1986</risdate><volume>35</volume><issue>9</issue><spage>T76</spage><epage>T79</epage><pages>T76-T79</pages><issn>0525-1931</issn><abstract>A powdered (agate pot and vibrating mixer mill is used) sample (0.2g) is decomposed with a mixed acid solution (15ml of hydrochloric acid +1ml of hydrofluoric acid) in a Teflon bomb. When the resultant solution is diluted directly with water, large quantities of precipitates (consisting of titanium, zirconium and lead compounds etc.) are observed. To avoid this, the following procedure is employed; The solution is transferred into a polyethylene beaker containing 1.5g of citric acid. After pH adjustment to 89, most of the precipitates can be dissolved by the addition of 2.0g of EDTA·2Na. The remaining LaF3 precipitate is dissolved by heating with 1.5g of boric acid and 20 ml of nitric acid. After cooling, this solution is used for rinsing the bomb, and is transferred into a 250ml volumetric flask. An aliquot of 25ml is diluted four times with water and analysed by ICP-AES. The procedure described here provides a rapid and precise (R.S.D.<3%) determination for all elements (Ti, Zr, Pb, Nb, Sr, La, Cr, Mn and Mg) without erosion of glassware and quartzware (plasma torch, nebulizer etc.).</abstract><cop>Tokyo</cop><pub>The Japan Society for Analytical Chemistry</pub><doi>10.2116/bunsekikagaku.35.9_T76</doi><oa>free_for_read</oa></addata></record> |
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| ispartof | BUNSEKI KAGAKU, 1986/09/05, Vol.35(9), pp.T76-T79 |
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| language | eng ; jpn |
| recordid | cdi_proquest_journals_1448897931 |
| source | J-STAGE Free; Freely Accessible Japanese Titles; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | chromium determination of niobium ICP-AES lanthanum lead zirconate titanate analysis manganese and magnesium strontium |
| title | Determination of titanium, zirconium, lead and additives in lead zirconate titanate by ICP-AES |
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